Marc Visseaux

Catalyse et Chimie Moléculaire
Méthodologie organométallique pour la catalyse homogène (MOCAH)

Professeur des Universités

(Enseignants chercheurs)

Thèmes de recherche

• Catalyse de polymérisation : étude et mise en œuvre de nouveaux systèmes catalytiques homogènes. Génération « in situ » d’espèces catalytiques. Etude des mécanismes réactionnels de polymérisation (RMN , Maldi-Tof). Calculs DFT.

• Elaboration de polymères et copolymères à structure contrôlée. Etudes physico-chimiques

• Chimie organométallique (en particulier Terres Rares) : synthèse à façon de nouveaux catalyseurs pour la polymérisation, espèces réactives, corrélations structure-propriétés en solution.

Recherches actuelles – résultats marquants

• Valorisation des borohydrures de terres rares (post-metallocènes, hémi-métallocènes, métallocènes) pour la polymérisation contrôlée (sélectivité, grandeurs macromoléculaires) des diènes conjugués (isoprène), du styrène, et de l’éthylène.

• mise au point d’une méthode (la « borohydride alkyl-route ») permettant la synthèse de catalyseurs par voie directe, et l’évaluation rapide de l’impact d’un ligand en catalyse de polymérisation.

• Elaboration de nouvelles familles de copolymères stéréoréguliers diène/styrène inédits

• 1ère « Catalysis Chain Growth » en polymérisation syndioselective du styrène

Parcours de recherche

depuis 11/2003 : Professeur des Universités 2eme cl. à l’Université des Sciences et Technologies de Lille (CNU 32) depuis 1/11/2003 (IUT "A", Villeneuve d’Ascq)

1993-2003 : Maître de Conférences à l’Université de Dijon à l’Ecole Supérieure d’Ingénieurs de REcherche en Matériaux (ESIREM) et au LSEO (UMR 5632 CNRS). 1ère Classe depuis 09/1998.

Titres universitaires (Université de Dijon) :

2000 : Habilitation à Diriger Des Recherches (6/12/2000)

1992 : Doctorat Chimie-Physique (25/09/1992). Alloc. M.R.T. Moniteur de l’Enst Supérieur 1990-92.

D.E.S. Céramiques et Plastiques (1990, mention B)

D.E.A. Chimie-Physique option Chimie Moléculaire (1989, major, mention B)

Activités d’enseignement

Responsable pédagogique Chimie-Physique générale (CM, TD, formation initiale et par apprentissage), IUT A Villeneuve d’Ascq.

Responsable de module (L9 Chimie Organique Industrielle) dans le cadre du Master Sciences de la Matière (M1, USTL). Catalyse Ziegler (M2, USTL).

Interventions à l’ENSCL (biopolymères).

Membre du Conseil de Dépt de Chimie de l’IUT A Villeneuve d’Ascq

Collaborations

• Rhodia Recherches et Technologies (Dr T. Mathivet, M. Destarac)

• Pr H. Chermette (UCB Lyon) ;

• Pr M.M. Kubicki (ICMUB, Dijon) ;

• Dr L. Brachais (EMMA, Dijon) ;

• Dr F. Nief (Ecole Polytechnique Palaiseau) ;

• Dr R. Duchateau (Eindhoven U. T., Pays-Bas) ;

• Dr T. Devic (Institut Lavoisier, Versailles) ;

• Prs A. El Bouadili et A. Hafid (L. C. A. E., Beni-Mellal, Maroc) ;

• Pr M.H. Garcia (FCUL Lisbonne, Portugal, thèse cotutelle A. Valente) ;

• Pr P. Mountford (Oxford, G.B.) ;

• Dr Y. Ngono-Rivache (CEA Caen).

Sélection de publications

Publicaciones en la base de datos: 54 (desde 2008)

• 2022

• Ferrocene/ferrocenium redox shuttling: Peroxide decomposition catalysis applied to vinyl monomers polymerization under suspension conditions.
  Zouhri Yassir, Berthé Jean-Michel M., Bonnet Fanny, Stasik Bernard, Colemonts Christel, Lasuye Thierry, Mortreux André, Champouret Yohan, Visseaux Marc.
  Polymer, vol. 260, pg. 125368 (2022) DOI
   
• Alkenes and Allyl Complexes of the Group 3 Metals and Lanthanides.
  Beauvois Maxime, Champouret Yohan, Bonnet Fanny, Visseaux Marc.
  undefined, pg. 382-448 (2022) DOI
   
• Homoleptic and Heteroleptic Substituted Amidomethylpyridine Iron Complexes: Synthesis, Structure and Polymerization ofrac‐Lactide .
  Hashmi Obaid H., Capet Frederic, Visseaux Marc, Champouret Yohan.
  European Journal of Inorganic Chemistry, (2022) DOI
   

• 2021

• Evidence of coordinative chain transfer polymerization of isoprene using iron iminopyridine/ZnEt2 catalytic systems.
  Hashmi Obaid H., Visseaux Marc, Champouret Yohan.
  Polymer Chemistry, vol. 12, pg. 4626-4631 (2021) DOI
   

• 2020

• Rationalizing the Reactivity of Mixed Allyl Rare-Earth Borohydride Complexes with DFT Studies.
  Fadlallah Sami, Jothieswaran Jashvini, Del Rosal Iker, Maron Laurent, Bonnet Fanny, Visseaux Marc.
  Catalysts, vol. 10, pg. 820 (2020) DOI
   
• Catalyzed chain growth polymerisation of ethylene using lanthanidocenes/dialkylmagnesium: further developments and one pot synthesis of narrow dispersed high molecular weight fatty alcohols.
  Chenal T., Drelon M., Marsh B., Silva F. F., Visseaux M., Mortreux A.
  Catalysis Science < Technology, vol. 10, pg. 6809-6824 (2020) DOI
   

• 2019

• Efficient One-Pot Synthesis of End-Functionalized trans-Stereoregular Polydiene Macromonomers.
  Georges Sébastien, Hashmi Obaid Hasan, Bria Marc, Zinck Philippe, Champouret Yohan, Visseaux Marc.
  Macromolecules, vol. 52, pg. 1210-1219 (2019) DOI
   
• Discrete iron-based complexes: Applications in homogeneous coordination-insertion polymerization catalysis.
  Champouret Yohan, Hashmi Obaid H., Visseaux Marc.
  Coordination Chemistry Reviews, vol. 390, pg. 127-170 (2019) DOI
   
• Highly Active Iminopyridyl Iron-Based Catalysts for the Polymerization of Isoprene.
  Hashmi Obaid H., Champouret Yohan, Visseaux Marc.
  Molecules, vol. 24, pg. 3024 (2019) DOI
   

• 2018

• Catalysts for the Controlled Polymerization of Conjugated Dienes.
  Visseaux Marc.
  Catalysts, vol. 8, pg. 442 (2018) DOI
   
• Catalytic metal-based systems for controlled statistical copolymerisation of lactide with a lactone.
  Stirling E., Champouret Y., Visseaux M.
  Polymer Chemistry, vol. 9, pg. 2517-2531 (2018) DOI
   

• 2017

• Bismuth tris-silylamide: A new non-toxic metal catalyst for the ring opening (co-)polymerization of cyclic esters under smooth conditions.
  Bonné Christophe, Pahwa Anish, Picard Charly, Visseaux Marc.
  Inorganica Chimica Acta, vol. 455, pg. 521-527 (2017) DOI
   
• Mixed Allyl Rare-Earth Borohydride Complexes: Synthesis, Structure, and Application in (Co-)Polymerization Catalysis of Cyclic Esters.
  Fadlallah Sami, Jothieswaran Jashvini, Capet Frédéric, Bonnet Fanny, Visseaux Marc.
  Chemistry - A European Journal, vol. 23, pg. 15644-15654 (2017) DOI
   
• Recent Advances in Rare Earth Complexes Bearing Allyl Ligands and Their Reactivity towards Conjugated Dienes and Styrene Polymerization.
  Jothieswaran Jashvini, Fadlallah Sami, Bonnet Fanny, Visseaux Marc.
  Catalysts, vol. 7, pg. 378 (2017) DOI
   

• 2016

• Telomerization of 1,3-butadiene with glycerol carbonate and subsequent ring-opening lactone co-polymerization.
  Ibn El Alami Mohammed Samir, Suisse Isabelle, Fadlallah Sami, Sauthier Mathieu, Visseaux Marc.
  Comptes Rendus Chimie, vol. 19, pg. 299-305 (2016) DOI
   
• A new series of trivalent lanthanide (Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy) coordination polymers with a 1,2-cyclohexanedicarboxylate ligand: synthesis, crystal structure, luminescence and catalytic properties.
  Russell Samantha E., Gosset Cyrille, Agache Xavier, Volkringer Christophe, Henry Natacha, Decadt Roel, Van Deun Rik, Visseaux Marc, Loiseau Thierry.
  CrystEngComm, vol. 18, pg. 3594-3605 (2016) DOI
   
• Mixed Allyl–Borohydride Lanthanide Complexes: Synthesis of Ln(BH4)2(C3H5)(THF)3(Ln = Nd, Sm), Characterization, and Reactivity toward Polymerization.
  Fadlallah Sami, Terrier Michaël, Jones Chloe, Roussel Pascal, Bonnet Fanny, Visseaux Marc.
  Organometallics, vol. 35, pg. 456-461 (2016) DOI
   
• β-Diketiminate-supported magnesium alkyl: synthesis, structure and application as co-catalyst for polymerizations mediated by a lanthanum half-sandwich complex.
  Georges Sébastien, Bonnet Fanny, Roussel Pascal, Visseaux Marc, Zinck Philippe.
  Applied Organometallic Chemistry, vol. 30, pg. 26-31 (2016) DOI
   

• 2015

• Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis.
  Russell Samantha, Loiseau Thierry, Volkringer Christophe, Visseaux Marc.
  Inorganics, vol. 3, pg. 467-481 (2015) DOI
   
• Bis(phenolate)amine-supported lanthanide borohydride complexes for styrene and trans-1,4-isoprene (co-)polymerisations.
  Bonnet Fanny, Dyer Hellen E., El Kinani Yassine, Dietz Carin, Roussel Pascal, Bria Marc, Visseaux Marc, Zinck Philippe, Mountford Philip.
  Dalton Trans., vol. 44, pg. 12312-12325 (2015) DOI
   

• 2014

• Isoprene-Styrene Chain Shuttling Copolymerization Mediated by a Lanthanide Half-Sandwich Complex and a Lanthanidocene: Straightforward Access to a New Type of Thermoplastic Elastomers.
  Valente Andreia, Stoclet Gregory, Bonnet Fanny, Mortreux André, Visseaux Marc, Zinck Philippe.
  Angewandte Chemie International Edition, vol. 53, pg. 1-5 (2014) DOI
   
• Coordinative Chain Transfer Copolymerization and Terpolymerization of Conjugated Dienes.
  Georges Sébastien, Touré Ahmed Osmane, Visseaux Marc, Zinck Philippe.
  Macromolecules, vol. 47, pg. 4538-4547 (2014) DOI
   
• Polymyrcene microstructure revisited from precise high-field nuclear magnetic resonance analysis.
  Georges Sébastien, Bria Marc, Zinck Philippe, Visseaux Marc.
  Polymer, vol. 55, pg. 3869-3878 (2014) DOI
   
• Highly efficient cis-1,4 polymerisation of isoprene using simple homoleptic amido rare earth-based catalysts.
  Martins Nuno, Bonnet Fanny, Visseaux Marc.
  Polymer, vol. 55, pg. 5013-5016 (2014) DOI
   

• 2013

• (t-BuC5H4)3Nd: A triscyclopentadienyl rare earth compound as non-classical isoprene polymerization pre-catalyst.
  Rodrigues Ines, Xue Tan Yong, Roussel Pascal, Visseaux Marc.
  Journal of Organometallic Chemistry, vol. 743, pg. 139-146 (2013) DOI
   
• Tuning the catalytic properties of rare earth borohydrides for the polymerisation of isoprene.
  Bonnet Fanny, Jones Chloe E., Semlali Sanaa, Bria Marc, Roussel Pascal, Visseaux Marc, Arnold Polly L.
  Dalton Transactions, vol. 42, pg. 790 (2013) DOI
   
• Coordinative Chain Transfer Polymerization.
  Valente Andreia, Mortreux André, Visseaux Marc, Zinck Philippe.
  Chemical Reviews, vol. 113 (5), pg. 130207123620002 (2013) DOI
   
• Uranium(iv) amido-borohydrides as highly active diene polymerisation catalysts.
  Mansell Stephen M., Bonnet Fanny, Visseaux Marc, Arnold Polly L.
  Dalton Transactions, vol. 42, pg. 9033 (2013) DOI
   
• Trans-stereospecific polymerization of butadiene and random copolymerization with styrene using borohydrido neodymium/magnesium dialkyl catalysts.
  Ventura A., Chenal T., Bria M., Bonnet F., Zinck P., Ngono-Ravache Y., Balanzat E., Visseaux M.
  European Polymer Journal, vol. 49, pg. 4130-4140 (2013) DOI
   

• 2012

• Water-Free Neodymium 2,6-Naphthalenedicarboxylates Coordination Complexes and Their Application as Catalysts for Isoprene Polymerization.
  Rodrigues Inês, Mihalcea Ionut, Volkringer Christophe, Loiseau Thierry, Visseaux Marc.
  Inorganic Chemistry, vol. 51, pg. 483-490 (2012) DOI
   
• Highly stereoselective coordination polymerization of β-myrcene from a lanthanide-based catalyst: Access to bio-sourced elastomers.
  Loughmari Saliha, Hafid Abderrafia, Bouazza Aicha, El Bouadili Abdelaziz, Zinck Philippe, Visseaux Marc.
  Journal of Polymer Science Part A: Polymer Chemistry, vol. 50, pg. 2898-2905 (2012) DOI
   
• Isoprene polymerization using a neodymium phenolate pre-catalyst combined to aluminum based co-catalysts.
  Vitorino M.J., Zinck P., Visseaux M.
  European Polymer Journal, vol. 48, pg. 1289-1294 (2012) DOI
   
• Combining Polyethylene CCG and Stereoregular Isoprene Polymerization: First Synthesis of Poly(ethylene)-b-(trans-isoprene) by Neodymium Catalyzed Sequenced Copolymerization.
  Chenal Thomas, Visseaux Marc.
  Macromolecules, vol. 45, pg. 5718-5727 (2012) DOI
   

• 2011

• Borohydrido rare earth based coordinative chain transfer copolymerization: A convenient tool for tuning the microstructure of isoprene/styrene copolymers.
  Valente Andreia, Zinck Philippe, Mortreux André, Visseaux Marc.
  Journal of Polymer Science Part A: Polymer Chemistry, vol. 49, pg. 1615-1620 (2011) DOI
   
• Half-lanthanocene/dialkylmagnesium-mediated coordinative chain transfer copolymerization of styrene and hexene.
  Valente Andreia, Zinck Philippe, Mortreux Andre , Bria Marc, Visseaux Marc.
  Journal of Polymer Science Part A: Polymer Chemistry, vol. 49, pg. 3778-3782 (2011) DOI
   
• Polymerization of ɛ-caprolactone using ruthenium(II) mixed metallocene catalysts and isopropyl alcohol: Living character and mechanistic study.
  Valente Andreia, Zinck Philippe, Mortreux André, Visseaux Marc, Mendes Paulo J.G., Silva Tiago J.L., Garcia M. Helena.
  Journal of Molecular Catalysis A: Chemical, vol. 346, pg. 102-110 (2011) DOI
   
• Mechanistic Insights of the Initiation Process of the Ring-Opening Polymerization of ε-Caprolactone by Divalent Sm(BH4)2(THF)2with DFT: Concerted or Oxidative Reaction?.
  Iftner Christophe, Bonnet Fanny, Nief François, Visseaux Marc, Maron Laurent.
  Organometallics, vol. 30, pg. 4482-4485 (2011) DOI
   
• Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.
  Momin Aurélien, Bonnet Fanny, Visseaux Marc, Maron Laurent, Takats Josef, Ferguson Michael J., Le Goff Xavier-Frédéric, Nief François.
  Chemical Communications, vol. 47, pg. 12203 (2011) DOI
   
• Metal–Organic-Framework-Type 1D-Channel Open Network of a Tetravalent Uranium Trimesate.
  Volkringer Christophe, Mihalcea Ionut, Vigier Jean-François, Beaurain Arnaud, Visseaux Marc, Loiseau Thierry.
  Inorganic Chemistry, vol. 50, pg. 11865-11867 (2011) DOI
   
• Borohydride complexes of rare earths, and their applications in various organic transformations.
  Visseaux Marc, Bonnet Fanny.
  Coordination Chemistry Reviews, vol. 255, pg. 374-420 (2011) DOI
   

• 2010

• Rare earths/main group metal alkyls catalytic systems for the 1,4-trans stereoselective coordinative chain transfer polymerization of isoprene.
  Valente Andreia, Zinck Philippe, Vitorino Marta J., Mortreux A., Visseaux M.
  Journal of Polymer Science Part A: Polymer Chemistry, vol. 48, pg. 4640-4647 (2010) DOI
   
• A Joint Experimental/Theoretical Investigation of the Statistical Olefin/Conjugated Diene Copolymerization Catalyzed by a Hemi-Lanthanidocene [(Cp*)(BH4)LnR].
  Perrin Lionel, Bonnet Fanny, Chenal Thomas, Visseaux Marc, Maron Laurent.
  Chemistry - A European Journal, vol. 16, pg. 11376-11385 (2010) DOI
   
• Synthesis of samarium(ii) borohydrides and their behaviour as initiators in styrene and ε-caprolactone polymerisation.
  Jaroschik Florian, Bonnet Fanny, Le Goff Xavier-Frédéric, Ricard Louis, Nief François, Visseaux Marc.
  Dalton Transactions, vol. 39, pg. 6761 (2010) DOI
   
• Facile Synthesis of Lanthanidocenes by the “Borohydride/Alkyl Route” and Their Application in Isoprene Polymerization.
  Visseaux Marc, Terrier Michael, Mortreux André, Roussel Pascal.
  European Journal of Inorganic Chemistry, vol. 2010, pg. 2867-2876 (2010) DOI
   
• A DFT study of conjugated dienes polymerisation catalyzed by [Cp*ScR]+: insights into the propensity for cis-1,4 insertion.
  Perrin Lionel, Bonnet Fanny, Visseaux Marc, Maron Laurent.
  Chemical Communications, vol. 46, pg. 2965 (2010) DOI
   
• Reversible coordinative chain transfer polymerization of styrene by rare earth borohydrides, chlorides/dialkylmagnesium systems.
  Zinck Philippe, Valente Andreia, Bonnet Fanny, Violante Ana, Mortreux André, Visseaux Marc, Ilinca Simona, Duchateau Rob, Roussel Pascal.
  Journal of Polymer Science Part A: Polymer Chemistry, vol. 48, pg. 802-814 (2010) DOI
   

• 2009

• Lanthanide Metal-Organic Frameworks as Ziegler–Natta Catalysts for the Selective Polymerization of Isoprene.
  Vitorino Marta J., Devic Thomas, Tromp Moniek, Férey Gérard, Visseaux Marc.
  Macromolecular Chemistry and Physics, vol. 210, pg. 1923-1932 (2009) DOI
   
• Catalytic Chain Transfer (co-)Polymerization: Unprecedented Polyisoprene CCG and a New Concept to Tune the Composition of a Statistical Copolymer.
  Valente Andreia, Zinck Philippe, Mortreux André, Visseaux Marc.
  Macromolecular Rapid Communications, vol. 30, pg. 528-531 (2009) DOI
   
• On the number-average molecular weight of poly(1,4-trans isoprene) determined by conventional GPC.
  Zinck Philippe, Terrier Michaël, Mortreux André, Visseaux Marc.
  Polymer Testing, vol. 28, pg. 106-108 (2009) DOI
   
• Functionalization of syndiotactic polystyrene.
  Zinck Philippe, Bonnet Fanny, Mortreux André, Visseaux Marc.
  Progress in Polymer Science, vol. 34, pg. 369-392 (2009) DOI
   
• Unprecedented dual behaviour of a half-sandwich scandium-based initiator for both highly selective isoprene and styrene polymerisation.
  Bonnet Fanny, Da Costa Violante Cristina, Roussel Pascal, Mortreux André, Visseaux Marc.
  Chemical Communications, pg. 3380 (2009) DOI
   

• 2008

• Half-lanthanidocenes catalysts via the “borohydride/alkyl” route: A simple approach of ligand screening for the controlled polymerization of styrene.
  Zinck Philippe, Valente Andreia, Terrier Michaël, Mortreux André, Visseaux Marc.
  Comptes Rendus Chimie, vol. 11, pg. 595-602 (2008) DOI
   
• Cationic borohydrido–neodymium complex: Synthesis, characterization and its application as an efficient pre-catalyst for isoprene polymerisation.
  Visseaux Marc, Mainil Michael, Terrier Michael, Mortreux André, Roussel Pascal, Mathivet Thomas, Destarac Mathias.
  Dalton Transactions, pg. 4558 (2008) DOI
   
• New ionic half-metallocenes of early lanthanides.
  Visseaux M., Zinck P., Terrier M., Mortreux A., Roussel P.
  Journal of Alloys and Compounds, vol. 451, pg. 352-357 (2008) DOI