Recent work
Check our last article (dx.doi.org/10.1002/anie.201004310) on the use of « Heteronuclear NMR Correlations to Probe the Local Structure of Catalytically Active Surface Aluminum Hydride Species on γ-Alumina ».
This work is the result of a collaboration with Régis Gauvin (UCCS, Lille) and Mostafa Taoufik (CPE, Lyon) who have interest in the synthesis, characterisation and applications of grafted catalysts. Here, we have synthesized aluminum hydrides supported on partially dehydroxylated alumina, through the hydrogenolysis of grafted alkyl precursors. The multinuclear NMR study has revealed that these species are characterised by a strong dipolar and scalar coupling between 1H and 27Al nuclei. In HMQC correlations Al–H entities were identified by filtering out the signal of the Al2O3 bulk. These main-group-metal hydrides catalyze both ethylene polymerization and hydrogenation.
Research Activities
Main Scientific Contributions
I have been member of the NMR and Applications group of the UCCS laboratory (Dir. Profs Lionel Montagne & Jean-Paul Amoureux) since November 2002. My activity has been equally shared between the development of new methods for solid-State NMR and the applications of NMR to the structure determination of glasses and crystalline materials in solid-state chemistry.
In NMR methodology, I have participated in the improvement of the sensitivity of the MQMAS experiments by introducing the SPAM concept. This research project was motivated by the PhD work of A. Flambard, that concentrated on the NMR-study of niobiophosphate glasses (for non-linear optical applications). I have also proposed a new decoupling sequence dedicated to quadrupolar nuclei [Delevoye, 2007] in order to decouple efficiently the scalar coupling which sometimes broadens resonances due to the coupling of central and satellite transitions of a quadrupolar nucleus. In parallel, I have participated in several projects where NMR was a key element in the structural study of crystalline, amorphous or disordered materials. I am one of the main researchers, at the origin of the transversal axis (NMR and modelling), which was initiated in 2006 after our laboratories merged to become the UCCS.
With the recent new developments in the domain of DFT calculations of NMR parameters (chemical shifts, quadrupolar parameters, etc.), I have also created a transversal research program with another group within the UCCS, Modelling and Spectroscopy (Prof. J-F Paul and Dr S. Cristol). Our collaboration has led to the publication of several articles where the combination of NMR and the ab initio approach has played a key role in the interpretation of the NMR results in terms of structural parameters within the materials. In 2009, F. Vasconcelos completed his PhD with us on the “first Principles NMR in 17O, applied to the study of crystalline and amorphous phosphates. He revealed in sodium phosphate materials, the long-, medium- and short-range influence of 17O chemical shift, quadrupolar coupling constant CQ and asymmetry parameter Q, respectively. His results include a first evidence of long-range disorder and short-range ordering through the distribution of NMR parameters in a phosphate glass. Since 2007, N. Forler continued our combined approach by investigating the process of water weathering of a phosphate glass by a multinuclear NMR study. In particular, we have calculated NMR parameters for protonated sodium phosphate crystalline phases and showed the strong correlation between NMR parameters and the type of proton bondings in phosphates.
Background
I have a background in material science and a strong experience in the field of methodology and applications of solid-state NMR. During my PhD with Prof. Amoureux (1995-98), I participated in the exciting development of high-resolution experiments for quadrupolar nuclei (MQMAS) through my contribution to the development of a method of quantification for MQMAS spectra, and through it applications to microporous materials.
After one year of teaching physics (TD, practicals) at the IUT Chimie (Lille), I worked for three years for the Bruker BioSpin company, a manufacturer of NMR spectrometer, where I provided customers with scientific advice on methodology and applications in solid-state NMR. After this industrial experience, I joined the research group “NMR and Glasses” in the UCCS in 2002.
Bibliography
Publicaciones en la base de datos: 73 (desde 2008) 2023- Examining a Year-Long Chemical Degradation Process and Reaction Kinetics in Pristine and Defect-Passivated Lead Halide Perovskites.
Raval Parth, Akhavan Kazemi Mohammad Ali, Ruellou Julie, Trébosc Julien, Lafon Olivier, Delevoye Laurent, Sauvage Frédéric, Manjunatha Reddy G. N.
Chemistry of Materials, vol. 35, pg. 2904-2917 (2023)  DOI
- Boron Adsorption Kinetics of Microcrystalline Cellulose and Polymer Resin.
Raval Parth, Thomas Neethu, Hamdouna Lama, Delevoye Laurent, Lafon Olivier, Manjunatha Reddy G. N.
Langmuir, vol. 39, pg. 5384-5395 (2023) DOI
2021- Investigating the active phase of Ca-based glycerol polymerization catalysts: On the importance of calcium glycerolate.
Ebadi Pour Negisa, Dumeignil Franck, Katryniok Benjamin, Delevoye Laurent, Revel Bertrand, Paul Sébastien.
Molecular Catalysis, vol. 507, pg. 111571 (2021) DOI
2020- Defect Passivation via the Incorporation of Tetrapropylammonium Cation Leading to Stability Enhancement in Lead Halide Perovskite.
Krishna Anurag, Akhavan Kazemi Mohammad Ali, Sliwa Michel, Reddy G. N. Manjunatha, Delevoye Laurent, Lafon Olivier, Felten Alexandre, Do Mai Trang, Gottis Sébastien, Sauvage Frédéric.
Advanced Functional Materials, vol. 30, pg. 1909737 (2020) DOI
2019- A smarter approach to catalysts by design: Combining surface organometallic chemistry on oxide and metal gives selective catalysts for dehydrogenation of 2,3-dimethylbutane.
Rouge Pascal, Garron Anthony, Norsic Sébastien, Larabi Cherif, Merle Nicolas, Delevoye Laurent, Gauvin Regis M., Szeto Kai C., Taoufik Mostafa.
Molecular Catalysis, vol. 471, pg. 21-26 (2019) DOI
- Grafting of a new bis-silylamido aluminum species on silica: insight from solid-state NMR into interactions with the surface.
Vancompernolle Tom, Merle Nicolas, Capet Frédéric, Del Rosal Iker, Laurent Maron, Delevoye Laurent, Pourpoint Frédérique, Gauvin Régis M.
Dalton Transactions, vol. 48, pg. 5243-5252 (2019) DOI
2018- Molybdenum Influence on the Mixed-Alkali Effect of Lithium–Sodium Phosphate Glasses.
Pereira Luiz F. P., Bodiang Kadiali, Nunes Eduardo H. M., Mear François O., Delevoye Laurent, Montagne Lionel.
The Journal of Physical Chemistry C, vol. 122, pg. 15886-15891 (2018) DOI
- Enhanced Metathesis Activity and Stability of Methyltrioxorhenium on a Mostly Amorphous Alumina: Role of the Local Grafting Environment.
Zhang Fan, Szeto Kai C., Taoufik Mostafa, Delevoye Laurent, Gauvin Régis M., Scott Susannah L.
Journal of the American Chemical Society, vol. 140, pg. 13854-13868 (2018) DOI
- A Strong Support Effect in Selective Propane Dehydrogenation Catalyzed by Ga(i-Bu)3 Grafted onto γ-Alumina and Silica.
Szeto Kai C., Jones Zachary R., Merle Nicolas, Rios César, Gallo Alessandro, Le Quemener Frederic, Delevoye Laurent, Gauvin Régis M., Scott Susannah L., Taoufik Mostafa.
ACS Catalysis, vol. 8, pg. 7566-7577 (2018) DOI
- Synthesis of an oxo trialkyl tungsten fluoride complex and its dual reactivity with silica dehydroxylated at high temperature.
Merle Nicolas, Mazoyer Etienne, Szeto Kai C., Rouge Pascal, de Mallmann Aimery, Berrier Elise, Delevoye Laurent, Gauvin Régis M., Nicholas Christopher P., Basset Jean-Marie, Taoufik Mostafa.
Journal of Organometallic Chemistry, vol. 869, pg. 11-17 (2018) DOI
- Solid-state NMR of quadrupolar nuclei for investigations into supported organometallic catalysts: scope and frontiers.
Grekov D., Vancompernolle T., Taoufik M., Delevoye L., Gauvin R. M.
Chemical Society Reviews, vol. 47, pg. 2572-2590 (2018) DOI
2017- Mixed Ba 1−x La x F 2+x fluoride materials as catalyst for the gas phase fluorination of 2-chloropyridine by HF.
Astruc A., Célérier S., Pavon E., Mamede A.-S., Delevoye L., Brunet S.
Applied Catalysis B: Environmental, vol. 204, pg. 107-118 (2017) DOI
- On the use of solid-state 45Sc NMR for structural investigations of molecular and silica-supported scandium amide catalysts.
Vancompernolle T., Trivelli X., Delevoye L., Pourpoint F., Gauvin R. M.
Dalton Trans., vol. 46, pg. 13176-13179 (2017) DOI
- Preparation of monopodal and bipodal aluminum surface species by selective protonolysis of highly reactive [AlH3(NMe2Et)] on silica.
Sauter D. W., Chiari V., Aykac N., Bouaouli S., Perrin L., Delevoye L., Gauvin R. M., Szeto K. C., Boisson C., Taoufik M.
Dalton Trans., vol. 46, pg. 11547-11551 (2017) DOI
- 31 P MAS NMR spectroscopy with 93 Nb decoupling and DFT calculations: A structural characterization of defects in a niobium-phosphate phase.
Girard Guillaume, Vasconcelos Filipe, Montagne Lionel, Delevoye Laurent.
Solid State Nuclear Magnetic Resonance, vol. 84, pg. 210-215 (2017) DOI
- Well defined molybdenum oxo alkyl complex supported on silica by surface organometallic chemistry: A highly active olefin metathesis pre-catalyst.
Merle Nicolas, Le Quéméner Frédéric, Bouhoute Yassine, Szeto Kai C., De Mallmann Aimery, Barman Samir, Samantaray Manoja K, Delevoye Laurent, Gauvin Régis M., Taoufik Mostafa, Basset Jean Marie.
Journal of the American Chemical Society, vol. 139, pg. 2144-2147 (2017) DOI
2016- Solvent-Free Ring-Opening Metathesis Polymerization of Norbornene over Silica-Supported Tungsten-Oxo Perhydrocarbyl Catalysts.
Larabi Cherif, Szeto Kai C., Bouhoute Yassine, Charlin Marc O., Merle Nicolas, Mallmann Aimery De, Gauvin Regis M., Delevoye Laurent, Taoufik Mostafa.
Macromolecular Rapid Communications, vol. 37, pg. 1832-1836 (2016) DOI
- Modification of silica-supported tungsten neosilyl oxo precatalysts: impact of substituted phenol on activity and stability in olefin metathesis.
Bouhoute Y., Del Rosal I., Szeto K. C., Merle N., Grekov D., De Mallmann A., Le Roux E., Delevoye L., Gauvin R. M., Maron L., Taoufik M.
Catal. Sci. Technol., vol. 6, pg. 8532-8539 (2016) DOI
- 17O MAS NMR studies of oxo-based olefin metathesis catalysts: a critical assessment of signal enhancement methods.
Grekov D., Bouhoute Y., Del Rosal I., Maron L., Taoufik M., Gauvin R. M., Delevoye L.
Phys. Chem. Chem. Phys., vol. 18, pg. 28157-28163 (2016) DOI
- Macromol. Rapid Commun. 22/2016.
Larabi Cherif, Szeto Kai C., Bouhoute Yassine, Charlin Marc O., Merle Nicolas, Mallmann Aimery De, Gauvin Regis M., Delevoye Laurent, Taoufik Mostafa.
Macromolecular Rapid Communications, vol. 37, pg. 1848-1848 (2016) DOI
- Silica-Supported Tungsten Neosilyl Oxo Precatalysts: Impact of the Podality on Activity and Stability in Olefin Metathesis.
Grekov D., Bouhoute Y., Szeto K. C., Merle N., De Mallmann A., Lefebvre F., Lucas C., Del Rosal I., Maron L., Gauvin R. M., Delevoye L., Taoufik M.
Organometallics, vol. 35 (13), pg. 2188-2196 (2016) DOI
- Ligand exchange-mediated activation and stabilization of a Re-based olefin metathesis catalyst by chlorinated alumina.
Gallo Alessandro, Fong Anthony, Szeto Kai Chung, Rieb Julia, Delevoye Laurent, Gauvin Régis M., Taoufik Mostafa, Peters Baron, Scott Susannah L.
Journal of the American Chemical Society, vol. 138(39), pg. 12935-12947 (2016) DOI
- Silica/MAO/(n-BuCp)2ZrCl2catalyst: effect of support dehydroxylation temperature on the grafting of MAO and ethylene polymerization.
Bashir Muhammad Ahsan, Vancompernolle Tom, Gauvin Régis M., Delevoye Laurent, Merle Nicolas, Monteil Vincent, Taoufik Mostafa, McKenna Timothy F. L., Boisson Christophe.
Catal. Sci. Technol., vol. 6, pg. 2962-2974 (2016) DOI
- The design of a bipodal bis(pentafluorophenoxy)aluminate supported on silica as an activator for ethylene polymerization using surface organometallic chemistry.
Sauter Dominique W., Popoff Nicolas, Bashir Muhammad Ahsan, Szeto Kai C., Gauvin Régis M., Delevoye Laurent, Taoufik Mostafa, Boisson Christophe.
Chemical Communications, vol. 52, pg. 4776-4779 (2016) DOI
- Development of silica-supported frustrated Lewis pairs: highly active transition metal-free catalysts for the Z-selective reduction of alkynes.
Szeto Kai C., Sahyoun Wissam, Merle Nicolas, Castelbou Jessica Llop, Popoff Nicolas, Lefebvre Frédéric, Raynaud Jean, Godard Cyril, Claver Carmen, Delevoye Laurent, Gauvin Régis M., Taoufik Mostafa.
Catal. Sci. Technol., vol. 6, pg. 882-889 (2016) DOI
- Accessing Realistic Models for the WO3–SiO2Industrial Catalyst through the Design of Organometallic Precursors.
Bouhoute Y., Grekov D., Szeto K. C., Merle N., De Mallmann A., Lefebvre F., Raffa G., Del Rosal I., Maron L., Gauvin R. M., Delevoye L., Taoufik M.
ACS Catalysis, pg. 1-18 (2016) DOI
2015- Selective Grafting of Ga(i-Bu)3on the Silanols of Mesoporous H-ZSM-5 by Surface Organometallic Chemistry.
Szeto Kai C., Gallo Alessandro, Hernández-Morejudo Selene, Olsbye Unni, De Mallmann Aimery, Lefebvre Frédéric, Gauvin Régis M., Delevoye Laurent, Scott Susannah L., Taoufik Mostafa.
The Journal of Physical Chemistry C, vol. 119, pg. 26611-26619 (2015) DOI
- Effect of post treatment on the local structure of hierarchical Beta prepared by desilication and the catalytic performance in Friedel–Crafts alkylation.
Wang Yi, Sun Yinyong, Lancelot Christine, Lamonier Carole, Morin Jean-Charles, Revel Bertrand, Delevoye Laurent, Rives Alain.
Microporous and Mesoporous Materials, vol. 206, pg. 42-51 (2015) DOI
- Selective Secondary Face Modification of Cyclodextrins by Mechanosynthesis.
Menuel Stéphane, Doumert Bertrand, Saitzek Sébastien, Ponchel Anne, Delevoye Laurent, Monflier Eric, Hapiot Frédéric.
The Journal of Organic Chemistry, vol. 80, pg. 6259-6266 (2015) DOI
2014- Direct evidence of Lowenstein's rule violation in swelling high-charge micas.
Pavón E., Osuna F. J., Alba M. D., Delevoye L.
Chemical Communications, vol. 50, pg. 6984 (2014) DOI
- Well-Defined Supported Mononuclear Tungsten Oxo Species as Olefin Metathesis Pre-Catalysts.
Bouhoute Yassine, Garron Anthony, Grekov Denys, Merle Nicolas, Szeto Kai C., De Mallmann Aimery, Del Rosal Iker, Maron Laurent, Girard Guillaume, Gauvin Régis M., Delevoye Laurent, Taoufik Mostafa.
ACS Catalysis, vol. 4, pg. 4232-4241 (2014) DOI
- Labile Degree of Disorder in Bismuth-Oxophosphate Compounds: Illustration through Three New Structural Types.
Aliev A., Endara D., Huvé M., Colmont M., Roussel P., Delevoye L., Tran T.T., Halasyamani P.S., Mentré O.
Inorganic Chemistry, vol. 53, pg. 861-871 (2014) DOI
- An Investigation of Chlorine Ligands in Transition-Metal Complexes via35Cl Solid-State NMR and Density Functional Theory Calculations.
O’Keefe Christopher A., Johnston Karen E., Sutter Kiplangat, Autschbach Jochen, Gauvin Régis, Trébosc Julien, Delevoye Laurent, Popoff Nicolas, Taoufik Mostafa, Oudatchin Konstantin, Schurko Robert W.
Inorganic Chemistry, vol. 53, pg. 9581-9597 (2014) DOI
- Enforcing Z-selectivity in olefin metathesis through use of catalysts grafted on well-defined phenolic hybrid material.
Popoff Nicolas, Szeto Kai C., Merle Nicolas, Espinas Jeff, Pelletier Jérémie, Lefebvre Frederic, Thivolle-Cazat Jean, Delevoye Laurent, De Mallmann Aimery, Gauvin Regis M., Taoufik Mostafa.
Catalysis Today, vol. 235, pg. 41-48 (2014) DOI
- Heteronuclear NMR Spectroscopy as a Surface-Selective Technique: A Unique Look at the Hydroxyl Groups of γ-Alumina..
Taoufik Mostafa, Szeto Kai C., Merle Nicolas, Rosal Iker Del, Maron Laurent, Trébosc Julien, Tricot Grégory, Gauvin Régis M., Delevoye Laurent.
Chemistry - A European Journal, vol. 20, pg. 4038-4046 (2014) DOI
- The D-HMQC MAS-NMR Technique.
Tricot Gregory, Trébosc Julien, Pourpoint Frédérique, Gauvin Régis, Delevoye Laurent.
annu. Rep. NMR, vol. 81, pg. 145-184 (2014) DOI
2013- Design and Application of a Hybrid Material Featuring Well-Defined, Tuneable Grafting Sites for Supported Catalysis..
Popoff Nicolas, Espinas Jeff, Pelletier Jérémie, Szeto Kai C., Thivolle-Cazat Jean, Delevoye Laurent, Gauvin Régis M., Taoufik Mostafa.
ChemCatChem, vol. 5 (7), pg. 1971-1977 (2013) DOI
- Structure of Nb2O5–NaPO3 glasses by X-ray and neutron diffraction.
Hoppe U., Delevoye L., Montagne L., Zimmermann M. v., Hannon A. C.
Physical Chemistry Chemical Physics, vol. 15 (22), pg. 8520-8528 (2013) DOI
- New insights into the structure of oxynitride NaPON phosphate glasses by 17-oxygen NMR.
Muñoz F., Delevoye L., Montagne L., Charpentier T.
Journal of Non-Crystalline Solids, vol. 363, pg. 134-139 (2013) DOI
- Extended Czjzek model applied to NMR parameter distributions in sodium metaphosphate glass.
Vasconcelos Filipe, Cristol Sylvain, Paul Jean-François, Delevoye Laurent, Mauri Francesco, Charpentier Thibault, Le Caër Gérard.
Journal of Physics: Condensed Matter, vol. 25, pg. 255402 (2013) DOI
- A study of transition-metal organometallic complexes combining 35Cl solid-state NMR, 35Cl NQR and first-principles DFT calculations.
Johnston K E, O’Keefe C A, Gauvin R M, Trébosc J, Delevoye L, Amoureux J -P, Popoff N, Taoufik M, Oudatchin K, Schurko R W.
Chemistry - A European Journal, vol. 19, pg. 12396-12414 (2013) DOI
- 95Mo Solid-State Nuclear Magnetic Resonance Spectroscopy and Quantum Simulations: Synergetic Tools for the Study of Molybdenum Cluster Materials.
Cuny Jérôme, Cordier Stéphane, Perrin Christiane, Pickard Chris J., Delevoye Laurent, Trébosc Julien, Gan Zhehong, Pollès Laurent Le, Gautier Régis.
Inorganic Chemistry, vol. 52, pg. 617-627 (2013) DOI
- On the Track to Silica-Supported Tungsten Oxo Metathesis Catalysts: Input from17O Solid-State NMR.
Merle Nicolas, Girard Guillaume, Popoff Nicolas, De Mallmann Aimery, Bouhoute Yassine, Trébosc Julien, Berrier Elise, Paul Jean-François, Nicholas Christopher P., Del Rosal Iker, Maron Laurent, Gauvin Régis M., Delevoye Laurent, Taoufik Mostafa.
Inorganic Chemistry, vol. 52, pg. 10119-10130 (2013) DOI
- Vanadium Oxo Organometallic Species Supported on Silica for the Selective Non-oxidative Dehydrogenation of Propane.
Szeto Kai C., Loges Björn, Merle Nicolas, Popoff Nicolas, Quadrelli Alessandra, Jia Hongpeng, Berrier Elise, De Mallmann Aimery, Delevoye Laurent, Gauvin Régis M., Taoufik Mostafa.
Organometallics, vol. 32, pg. 6452-6460 (2013) DOI
2012- 17O NMR Gives Unprecedented Insights into the Structure of Supported Catalysts and Their Interaction with the Silica Carrier.
Merle Nicolas, Trébosc Julien, Baudouin Anne, Rosal Iker Del, Maron Laurent, Szeto Kai, Genelot Marie, Mortreux André, Taoufik Mostafa, Delevoye Laurent, Gauvin Régis M.
Journal of the American Chemical Society, vol. 134, pg. 9263-9275 (2012) DOI
- Observation of proximities between spin-1∕2 and quadrupolar nuclei: Which heteronuclear dipolar recoupling method is preferable?.
Lu X., Lafon O., Trébosc J., Tricot G., Delevoye L., Méar F., Montagne L., Amoureux J. P.
The Journal of Chemical Physics, vol. 137, pg. 144201 (2012) DOI
- Structure and properties of lead tungstate phosphate glasses.
Koudelka Ladislav, Šubčík Jiří, Mošner Petr, Gregora Ivan, Montagne Lionel, Delevoye Laurent.
Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, vol. 53 (3), pg. 86–92 (2012)
- Glass-forming ability and structure of glasses in the ZnO–WO3–P2O5 system.
Koudelka Ladislav, Šubčík Jiří, Mošner Petr, Gregora Ivan, Montagne Lionel, Delevoye Laurent.
Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, vol. 53 (3), pg. 79–85 (2012)
- Fine Hierarchy of the V–O Bonds by Advanced Solid State NMR: Novel Pb4(VO2)(PO4)3Structure as a Textbook Case.
Tricot Grégory, Mentré Olivier, Cristol Sylvain, Delevoye Laurent.
Inorganic Chemistry, vol. 51, pg. 13108-13113 (2012) DOI
- Triclinic–Cubic Phase Transition and Negative Expansion in the Actinide IV (Th, U, Np, Pu) Diphosphates.
Wallez Gilles, Raison Philippe E., Dacheux Nicolas, Clavier Nicolas, Bykov Denis, Delevoye Laurent, Popa Karin, Bregiroux Damien, Fitch Andrew N., Konings Rudy J. M.
Inorganic Chemistry, vol. 51, pg. 4314-4322 (2012) DOI
2011- NMR investigation of the crystallization mechanism of LaF3 and NaLaF4 phases in aluminosilicate glasses.
Muñoz Francisco, de Pablos-Martín Araceli, Hémono Nicolas, Pascual María Jesús, Durán Alicia, Delevoye Laurent, Montagne Lionel.
Journal of Non-Crystalline Solids, vol. 357, pg. 1463-1468 (2011) DOI
- A Well-Defined Silica-Supported Lanthanum Bis(phosphinimino)methanide.
Revel Bertrand, Delevoye Laurent, Tricot Grégory, Rastätter Marcus, Kuzdrowska Magdalena, Roesky Peter W., Gauvin Régis M.
European Journal of Inorganic Chemistry, vol. 2011, pg. 1366-1369 (2011) DOI
- Structural characterisation of phosphate materials: new insights into the spatial proximities between phosphorus and quadrupolar nuclei using the D-HMQC MAS NMR technique.
Tricot G., Lafon O., Trébosc J., Delevoye L., Méar F., Montagne L., Amoureux J-P.
Physical Chemistry Chemical Physics, vol. 13, pg. 16786 (2011) DOI
- Aluminum Incorporation in TiO2Rutile at High Pressure: An XRD and High-Resolution27Al NMR Study.
Escudero Alberto, Delevoye Laurent, Langenhorst Falko.
The Journal of Physical Chemistry C, vol. 115, pg. 12196-12201 (2011) DOI
- Synthesis, Crystal and Electronic Structures, and Magnetic Properties of LiLn9Mo16O35 (Ln=La, Ce, Pr, and Nd) Compounds Containing the Original Cluster Mo16O36.
Gougeon Patrick, Gall Philippe, Cuny Jérôme, Gautier Régis, Le Pollès Laurent, Delevoye Laurent, Trébosc Julien.
Chemistry - A European Journal, vol. 17, pg. 13806-13813 (2011) DOI
- A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism.
Pelletier Jérémie, Espinas Jeff, Vu Nghiem, Norsic Sébastien, Baudouin Anne, Delevoye Laurent, Trébosc Julien, Le Roux Erwan, Santini Catherine, Basset Jean-Marie, Gauvin Régis M., Taoufik Mostafa.
Chemical Communications, vol. 47, pg. 2979 (2011) DOI
2010- New insights into oxygen environments generated during phosphate glass alteration: a combined 17O MAS and MQMAS NMR and first principles calculations study.
Forler Nina, Vasconcelos Filipe, Cristol Sylvain, Paul Jean-François, Montagne Lionel, Charpentier Thibault, Mauri Francesco, Delevoye Laurent.
Physical Chemistry Chemical Physics, vol. 12, pg. 9053 (2010) DOI
- Design of a well-defined, silica-supported chiral Zn scaffold for enantioselective catalysis.
Ternel Jérémy, Delevoye Laurent, Agbossou-Niedercorn Francine, Roisnel Thierry, Gauvin Régis M., Thomas Christophe M.
Dalton Transactions, vol. 39, pg. 3802 (2010) DOI
- Glass-forming ability and structure of ZnO–MoO3–P2O5 glasses.
Šubčík Jiří, Koudelka Ladislav, Mošner Petr, Montagne Lionel, Tricot Gregory, Delevoye Laurent, Gregora Ivan.
Journal of Non-Crystalline Solids, vol. 356, pg. 2509-2516 (2010) DOI
- First-principles calculations of NMR parameters for phosphate materials.
Vasconcelos Filipe, Cristol Sylvain, Paul Jean-François, Montagne Lionel, Mauri Francesco, Delevoye Laurent.
Magnetic Resonance in Chemistry, vol. 48, pg. S142-S150 (2010) DOI
- Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst.
Mazoyer Etienne, Merle Nicolas, Mallmann Aimery de, Basset Jean-Marie, Berrier Elise, Delevoye Laurent, Paul Jean-François, Nicholas Christopher P., Gauvin Régis M., Taoufik Mostafa.
Chemical Communications, vol. 46, pg. 8944 (2010) DOI
- Polymerization of racemic β-butyrolactone using supported catalysts: a simple access to isotactic polymers.
Ajellal Noureddine, Durieux Guillaume, Delevoye Laurent, Tricot Grégory, Dujardin Christophe, Thomas Christophe M., Gauvin Régis M.
Chemical Communications, vol. 46, pg. 1032 (2010) DOI
- Heteronuclear NMR Correlations To Probe the Local Structure of Catalytically Active Surface Aluminum Hydride Species on γ-Alumina.
Mazoyer Etienne, Trébosc Julien, Baudouin Anne, Boyron Olivier, Pelletier Jérémie, Basset Jean-Marie, Vitorino Marta J., Nicholas Christopher P., Gauvin Régis M., Taoufik Mostafa, Delevoye Laurent.
Angewandte Chemie International Edition, vol. 49, pg. 9854-9858 (2010) DOI
2009- Double-quantum NMR spectroscopy of 31P species submitted to very large CSAs.
Hu B., Delevoye L., Lafon O., Trébosc J., Amoureux J.P.
Journal of Magnetic Resonance, vol. 200, pg. 178-188 (2009) DOI
- Correlation NMR spectroscopy involving quadrupolar nuclei.
Amoureux J.P., Trébosc J., Delevoye L., Lafon O., Hu B., Wang Q.
Solid State Nuclear Magnetic Resonance, vol. 35, pg. 12-18 (2009) DOI
- Evidence of crystalline/glassy intermediates in bismuth phosphates.
Colmont Marie, Delevoye Laurent, Mentré Olivier.
New Journal of Chemistry, vol. 33, pg. 19-22 (2009) DOI
- Well-Defined Silica-Supported Calcium Reagents: Control of Schlenk Equilibrium by Grafting.
Gauvin Régis M., Buch Frank, Delevoye Laurent, Harder Sjoerd.
Chemistry - A European Journal, vol. 15, pg. 4382-4393 (2009) DOI
2008- Influence of phosphorus speciation on the phase separation of Na2O-B2O3-SiO2 glasses.
Munoz F, Montagne L, Delevoye L.
Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B, vol. 49 (6), pg. 339-345 (2008)
- 17O Solid-State NMR and First-Principles Calculations of Sodium Trimetaphosphate (Na3P3O9), Tripolyphosphate (Na5P3O10), and Pyrophosphate (Na4P2O7).
Vasconcelos Filipe, Cristol Sylvain, Paul Jean-Francois, Tricot Grégory, Amoureux Jean-Paul, Montagne Lionel, Mauri Francesco, Delevoye Laurent.
Inorganic Chemistry, vol. 47, pg. 7327-7337 (2008) DOI
- Structure and properties of potassium niobato-borophosphate glasses.
Koudelka Ladislav, Pospíšil Jaroslav, Mošner Petr, Montagne Lionel, Delevoye Laurent.
Journal of Non-Crystalline Solids, vol. 354, pg. 129-133 (2008) DOI
- Heteronuclear dipolar decoupling effects on multiple-quantum and satellite-transition magic-angle spinning NMR spectra.
Ganapathy S., Delevoye L., Amoureux J. P., Madhu P. K.
Magnetic Resonance in Chemistry, vol. 46, pg. 948-954 (2008) DOI
- MAS-NMR study of lithium zinc silicate glasses and glass-ceramics with various ZnO content.
Goswami Madhumita, Kothiyal Govind P., Montagne Lionel, Delevoye Laurent.
Journal of Solid State Chemistry, vol. 181, pg. 269-275 (2008) DOI
- Structure and nonlinear optical properties of sodium–niobium phosphate glasses.
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