Jeremy Dhainaut Catalyse Hétérogène Matériaux pour la catalyse (MATCAT) Chargé de Recherche (Chercheurs CNRS) Oficina: 108 (Edificio Autre) Teléfono: (+33) 03 20 43 47 95 Correo: Esta dirección de correo electrónico está siendo protegida contra los robots de spam. Necesita tener JavaScript habilitado para poder verlo.

Jérémy Dhainaut joined the CNRS in January 2019 as a researcher (Chargé de Recherche) at UCCS. Over his past experiences, both in academics and in industry, he developed an extended knowledge in the preparation and shaping of porous materials including zeolites, metal-organic frameworks (MOFs), and mesoporous silica. Nowadays his research is focused on the use of additive fabrication technologies for the preparation of catalysts and supports, especially for biomass valorisation.

Recent studies :

A commercial 3D printer was modified to prepare a variety of MOF-based solids with controlled morphologies from shear-thinning inks containing 2-hydroxyethyl cellulose. Four benchmark MOFs were tested for this purpose: HKUST-1, CPL-1, ZIF-8, and UiO-66-NH2. All solids are mechanically stable with up to 0.6 MPa of uniaxial compression and highly porous with BET specific surface areas lowered by 0 to -25%. Furthermore, these solids were applied to high-pressure hydrocarbon sorption (CH4, C2H4, and C2H6), for which they presented a consequent methane gravimetric uptake (UiO-66-NH2, ZIF-8, and HKUST-1) and a highly preferential adsorption of ethylene over ethane (CPL-1).

Current participation to :

• UPCAT technological platform (CPER-FEDER Archi-CM 3.2). UPCAT aims to support the upscaling of novel catalytic formulations for academics and industrials. UPCAT is equipped with up-to-date equipments for the synthesis, shaping, activation and characterization of catalysts up to the kilogram scale. More information on the website (in construction).
• RégCat (coordinator, STIMulE Volet Partenarial). This project is interested in building a strong collaboration between three regional laboratories (UCCS, LMCPA, TIMR), around research topics of mutual interest: 1/ granulation of hybrid materials, 2/ additive fabrication of ceramic supports, 3/ use of biobased templates for the synthesis of mesoporous organized supports.
• TEXMOF (ANR ASTRID). Within TEXMOF, the deposition of a thin layer of metal-organic frameworks on fabrics for toxic gas remediation is investigated.
• LOVOCAT (CPER PO FEDER IRenE 4). LOVOCAT is a joint project with an industrial, interested in the coupling of adsorption and catalysis for the efficient remediation of mixtures of COVs.
• CatReMo (ANR PRC). The CatReMo project aims at studying new efficient and robust routes for the solvothermal conversion of raw lignocellulosic biomass into added-value molecules, by using stable and reusable heterogeneous catalysts.

Publications :

Publicaciones en la base de datos: 31 (desde 2009)

• 2024

• Cytotoxicity and effectiveness of archetypal Metal-Organic Frameworks (HKUST-1, UiO-66, MIL-53, MIL-125) against coronaviruses (HCoV-229E and SARS-CoV-2).
  Plastiras Orfeas-Evangelos, Bouquet Peggy, Lecœur Cécile, Dhainaut Jérémy, Dacquin Jean-Philippe, Royer Sébastien, Loiseau Thierry, Goffard Anne, Volkringer Christophe.
  Microporous and Mesoporous Materials, vol. 367, pg. 112975 (2024) DOI
   
• On the role of cationic defects over the surface reactivity of manganite-based perovskites for low temperature catalytic oxidation of formaldehyde.
  Xu Yin, Dhainaut Jérémy, Dacquin Jean-Philippe, Lamonier Jean-François, Zhang Hui, Royer Sébastien.
  Applied Catalysis B: Environmental, vol. 342, pg. 123400 (2024) DOI
   

• 2023

• Enhanced Gas Adsorption in HKUST-1@Chitosan Aerogels, Cryogels, and Xerogels: An Evaluation Study.
  Hammi Nisrine, Bonneau Mickaele, El Kadib Abdelkrim, Kitagawa Susumu, Loiseau Thierry, Volkringer Christophe, Royer Sébastien, Dhainaut Jérémy.
  ACS Applied Materials < Interfaces, vol. 15, pg. 53395-53404 (2023) DOI
   
• Test Bench Development and Application to a Parametric Experimental Study on the Dynamic Adsorption Capacity of Noble Gases (Kr, Xe) in the Metal–Organic Framework HKUST-1.
  Nguyen-Sadassivame Julie, Massaloux Anaïs, Dhainaut Jérémy, Sarraf Riad, Chantereau Philippe, Cantrel Laurent, Loiseau Thierry, Volkringer Christophe, Nérisson Philippe.
  Industrial < Engineering Chemistry Research, vol. 62, pg. 20727-20740 (2023) DOI
   
• Unravelling the critical role of silanol in Pt/SiO2 for room temperature HCHO oxidation: An experimental and DFT study.
  Chen Shuo, Gueddida Saber, Badawi Michael, Lebègue Sébastien, Giraudon Jean-Marc, Dhainaut Jérémy, Royer Sébastien, Lamonier Jean-Francois.
  Applied Catalysis B: Environmental, vol. 331, pg. 122672 (2023) DOI
   
• Hierarchically porous ZIF-67/chitosan beads with high surface area and strengthened mechanical properties: Application to CO2 storage.
  Hammi N., Couzon N., Loiseau T., Volkringer C., El Kadib A., Royer S., Dhainaut J.
  Materials Today Sustainability, vol. 22, pg. 100394 (2023) DOI
   
• Enhancing ammonia catalytic production over spatially confined cobalt molybdenum nitride nanoparticles in SBA-15.
  Sfeir Amanda, Teles Camila A., Ciotonea Carmen, Reddy G.N. Manjunatha, Marinova Maya, Dhainaut Jérémy, Löfberg Axel, Dacquin Jean-Philippe, Royer Sébastien, Laassiri Said.
  Applied Catalysis B: Environmental, vol. 325, pg. 122319 (2023) DOI
   

• 2022

• Water-Based Synthesis of Zr6-Based Metal–Organic Framework Nanocrystals with Sulfonate Functions: Structural Features and Application to Fructose Dehydration.
  Yeskendir Bakytzhan, de Souza Priscilla M., Simon Pardis, Wojcieszak Robert, Courtois Christian, Lorgouilloux Yannick, Royer Sébastien, Dacquin Jean-Philippe, Dhainaut Jérémy.
  ACS Applied Nano Materials, vol. 5, pg. 14561-14571 (2022) DOI
   
• Assembly of SBA-15 into hierarchical porous monoliths replicating polymeric scaffolds.
  Yildiz Ridvan, Lorgouilloux Yannick, Dhainaut Jérémy, Ciotonea Carmen, Dacquin Jean-Philippe, Royer Sébastien, Courtois Christian.
  Microporous and Mesoporous Materials, vol. 337, pg. 111908 (2022) DOI
   
• Porous textile composites (PTCs) for the removal and the decomposition of chemical warfare agents (CWAs) – A review.
  Couzon Nelly, Dhainaut Jérémy, Campagne Christine, Royer Sébastien, Loiseau Thierry, Volkringer Christophe.
  Coordination Chemistry Reviews, vol. 467, pg. 214598 (2022) DOI
   
• Extrusion-Spheronization of UiO-66 and UiO-66_NH2 into Robust-Shaped Solids and Their Use for Gaseous Molecular Iodine, Xenon, and Krypton Adsorption.
  Abramova Alla, Couzon Nelly, Leloire Maëva, Nerisson Philippe, Cantrel Laurent, Royer Sébastien, Loiseau Thierry, Volkringer Christophe, Dhainaut Jérémy.
  ACS Applied Materials < Interfaces, vol. 14, pg. 10669-10680 (2022) DOI
   

• 2021

• Playing on 3D spatial distribution of Cu-Co (oxide) nanoparticles in inorganic mesoporous sieves: Impact on catalytic performance toward the cinnamaldehyde hydrogenation.
  Ciotonea Carmen, Chirieac Alexandru, Dragoi Brandusa, Dhainaut Jeremy, Marinova Maya, Pronier Stephane, Arii-Clacens Sandrine, Dacquin Jean-Philippe, Dumitriu Emil, Ungureanu Adrian, Royer Sébastien.
  Applied Catalysis A: General, vol. 623, pg. 118303 (2021) DOI
   
• From metal–organic framework powders to shaped solids: recent developments and challenges.
  Yeskendir Bakytzhan, Dacquin Jean-Philippe, Lorgouilloux Yannick, Courtois Christian, Royer Sébastien, Dhainaut Jérémy.
  Materials Advances, vol. 2, pg. 7139-7186 (2021) DOI
   
• Stability and radioactive gaseous iodine-131 retention capacity of binderless UiO-66-NH2 granules under severe nuclear accidental conditions.
  Leloire Maëva, Dhainaut Jérémy, Devaux Philippe, Leroy Olivia, Desjonqueres Hortense, Poirier Stéphane, Nerisson Philippe, Cantrel Laurent, Royer Sébastien, Loiseau Thierry, Volkringer Christophe.
  Journal of Hazardous Materials, vol. 416, pg. 125890 (2021) DOI
   
• La1-x(Sr, Na, K)xMnO3 perovskites for HCHO oxidation: The role of oxygen species on the catalytic mechanism.
  Xu Yin, Dhainaut Jérémy, Dacquin Jean-Philippe, Mamede Anne-Sophie, Marinova Maya, Lamonier Jean-François, Vezin Hervé, Zhang Hui, Royer Sébastien.
  Applied Catalysis B: Environmental, vol. 287, pg. 119955 (2021) DOI
   

• 2020

• Manipulating the physical states of confined ibuprofen in SBA-15 based drug delivery systems obtained by solid-state loading: Impact of the loading degree.
  Malfait Benjamin, Correia Natália T., Ciotonea Carmen, Dhainaut Jérémy, Dacquin Jean-Philippe, Royer Sébastien, Tabary Nicolas, Guinet Yannick, Hédoux Alain.
  The Journal of Chemical Physics, vol. 153, pg. 154506 (2020) DOI
   
• Phyllosilicate‐derived Nickel‐cobalt Bimetallic Nanoparticles for the Catalytic Hydrogenation of Imines, Oximes and N‐heteroarenes.
  Ciotonea Carmen, Hammi Nisrine, Dhainaut Jérémy, Marinova Maya, Ungureanu Adrian, El Kadib Abdelkrim, Michon Christophe, Royer Sébastien.
  ChemCatChem, (2020) DOI
   
• Flash Catalytic Pyrolysis of Polyethylene over (Alumino)silicate Materials.
  Klaimy Sophie, Ciotonea Carmen, Dhainaut Jérémy, Royer Sébastien, Casetta Mathilde, Duquesne Sophie, Tricot Grégory, Lamonier Jean‐François.
  ChemCatChem, vol. 12, pg. 1109-1116 (2020) DOI
   
• Hierarchical porous ε-MnO2 from perovskite precursor: Application to the formaldehyde total oxidation.
  Xu Yin, Dhainaut Jérémy, Rochard Guillaume, Dacquin Jean-Philippe, Mamede Anne-Sophie, Giraudon Jean-Marc, Lamonier Jean-François, Zhang Hui, Royer Sébastien.
  Chemical Engineering Journal, vol. 388, pg. 124146 (2020) DOI
   
• Formulation of Metal–Organic Framework Inks for the 3D Printing of Robust Microporous Solids toward High-Pressure Gas Storage and Separation.
  Dhainaut Jérémy, Bonneau Mickaële, Ueoka Ryota, Kanamori Kazuyoshi, Furukawa Shuhei.
  ACS Applied Materials < Interfaces, vol. 12, pg. 10983-10992 (2020) DOI
   

• 2018

• Synthesis and Shaping Scale-up Study of Functionalized UiO-66 MOF for Ammonia Air Purification Filters.
  Khabzina Yoldes, Dhainaut Jeremy, Ahlhelm Matthias, Richter Hans-Juergen, Reinsch Helge, Stock Norbert, Farrusseng David.
  Industrial < Engineering Chemistry Research, vol. 57, pg. 8200-8208 (2018) DOI
   

• 2017

• Systematic study of the impact of MOF densification into tablets on textural and mechanical properties.
  Dhainaut J., Avci-Camur C., Troyano J., Legrand A., Canivet J., Imaz I., Maspoch D., Reinsch H., Farrusseng D.
  CrystEngComm, vol. 19, pg. 4211-4218 (2017) DOI
   

• 2016

• A Reliable Method for the Preparation of Multiporous Alumina Monoliths by Ice-Templating.
  Dhainaut Jérémy, Deville Sylvain, Amirouche Idris, Klotz Michaela.
  Inorganics, vol. 4, pg. 6 (2016) DOI
   

• 2014

• The Use of Original Structure-Directing Agents for the Synthesis of EMC-1 Zeolite.
  Daou T.J., Dhainaut J., Chappaz A., Bats N., Harbuzaru B., Chaumeil H., Defoin A., Rouleau L., Patarin J.
  Oil < Gas Science and Technology – Revue d’IFP Energies nouvelles, vol. 70, pg. 447-454 (2014) DOI
   
• Synthesis of a New Diaazacrown Ether Compound Interconnected with an Azacrown Ether and Decorated with a Long Lipophilic Chain.
  Dhainaut Jérémy, Chappaz Alban, Bernard Didier, Chaumeil Hélène, Daou T. Jean, Defoin Albert, Rouleau Loïc, Bats Nicolas, Harbuzaru Bogdan, Patarin Joël.
  Synthetic Communications, vol. 44, pg. 1888-1892 (2014) DOI
   
• Freezing-induced ordering of block copolymer micelles.
  Dhainaut Jérémy, Piana Giulia, Deville Sylvain, Guizard Christian, Klotz Michaela.
  Chem. Commun., vol. 50, pg. 12572-12574 (2014) DOI
   

• 2013

• Synthesis of FAU and EMT-type zeolites using structure-directing agents specifically designed by molecular modelling.
  Dhainaut J., Daou T.J., Chappaz A., Bats N., Harbuzaru B., Lapisardi G., Chaumeil H., Defoin A., Rouleau L., Patarin J.
  Microporous and Mesoporous Materials, vol. 174, pg. 117-125 (2013) DOI
   
• The influence of l-lysine and PDADMA on the crystal size and porosity of zeolite Y material.
  Dhainaut Jérémy, Daou T. Jean, Bats Nicolas, Harbuzaru Bogdan, Lapisardi Grégory, Rouleau Loic, Patarin Joël.
  Microporous and Mesoporous Materials, vol. 170, pg. 346-351 (2013) DOI
   
• One-pot structural conversion of magadiite into MFI zeolite nanosheets using mononitrogen surfactants as structure and shape-directing agents.
  Dhainaut Jérémy, Daou T. Jean, Bidal Yannick, Bats Nicolas, Harbuzaru Bogdan, Lapisardi Grégory, Chaumeil Hélène, Defoin Albert, Rouleau Loïc, Patarin Joël.
  CrystEngComm, vol. 15, pg. 3009 (2013) DOI
   

• 2010

• Hierarchical macroporous–mesoporous SBA-15 sulfonic acidcatalysts for biodiesel synthesis.
  Dhainaut Jérémy, Dacquin Jean-Philippe, Lee Adam F., Wilson Karen.
  Green Chem., vol. 12, pg. 296-303 (2010) DOI
   

• 2009

• An Efficient Route to Highly Organized, Tunable Macroporous−Mesoporous Alumina.
  Dacquin Jean-Philippe, Dhainaut Jérémy, Duprez Daniel, Royer Sébastien, Lee Adam F., Wilson Karen.
  Journal of the American Chemical Society, vol. 131, pg. 12896-12897 (2009) DOI