Olivier Lafon

Solid State Chemistry Department
NMR and inorganic materials (RM2I)


Professeur des Universités

(Faculty researchers)


Phone:(+33) 03 74 95 13 36
Mail:This email address is being protected from spambots. You need JavaScript enabled to view it.
Address:Ecole Nationale Supérieure de Chimie de Lille
Cité Scientifique, Bâtiment C7 - BP 90108
59652 Villeneuve d'Ascq Cedex
France

Orcid: 0000-0002-5214-4060

Web of Science researcher ID: AAP-2177-2020

Research Group

NMR and inorganic materials (RM2I)

Fellowships and awards

2016 Junior member, Institut Universitaire de France, IUF (only 2% of French professors selected for research excellence, reduced teaching load and funding), Paris, France
2015 Chinese Academy of Sciences (CAS) President’s international fellowship (awarded to highly qualified international scientists, who conduct research with CAS researchers)
2013 Magnetic Resonance in Chemistry Award for Young Scientists, awarded to outstanding NMR researchers under the age of 40 by the scientific committee of Euromar (largest European conference on magnetic resonance)

Postdoctoral Fellows and graduate students

PhD students

 

2020 Lama Hamdouna
2019 Parth Raval
2019 Racha Bayzou
2019 Jessica Dawber 
2018 Jennifer S. Gomez 
2018 Florian Venel

 

Alumni

 

Former postdoctoral fellows

 

2018 - 2019 Andrew G. M. Rankin (post-doctoral fellow at LCMCP, Sorbonne-Univ/CNRS, Paris, France)
2018 - 2019 Piotr Paluch (assistant professor, Polish academy of sciences, Lodz, France)
2014 - 2016 Baudouin Dillmann (lecturer, ISEP, Paris, France)
2011 -2012

Frédérique Pourpoint (associate professor, Centrale Lille, France)

 

Former PhD students

 

2017 - 2020 Jean-Baptiste Alloko (teacher, Abidjan, Côte d'Ivoire)
2015 -2018   Raynald Giovine (postdoctoral fellow at UCSB, USA)
2014 - 2017   Hiroki Nagashima (research scientist at AIST, Japan)
2012 - 2015   Nghia T. Duong (postdoctoral researcher at RIKEN, Japan)
2012 - 2015   Yixuan Li (lecturer at Shanghai Univ. of international business and economics, P. R. China)
2012 - 2015   Shen Ming (associate professor at East China Normal Univ., Shanghai, P. R. China)
2011 - 2014   Aany Sofia Lilly Thankamony (postdoctoral fellow at TU Darmstadt, Germany)
2010 - 2013   Xingyu Lu (senior scientist at Westlake Univ., Hangzhou, P. R. China)
2007 - 2010   Qiang Wang (professor at Chinese Academy of Sciences, Wuhan, P. R. China)
2006 - 2009   Bingwen Hu (professor at East China Normal Univ., Shanghai, P. R. China)

Collaborations

Research Topics

Development of solid-state NMR spectroscopy to gain new insights into structure-property relationships of materials with applications in the field of bio-economy, energy and health.

 

Journal cover gallery

 

 

J. Phys. Chem. C 124, 6110-6120 (2020)

Chem. Eur. J. 23, 9525 (2017)

 ChemPhysChem 16, 1619 (2015) Analyst 139, 2702 (2014)  
   
Chem. Commun. 49, 2864 (2013) ChemPhysChem 13, 3562 (2012) Chem. Eur. J. 17, 6716 (2011)    

Current research areas

Novel NMR methods, notably for quadrupolar nuclei

 

Much of my work entails the development of novel NMR techniques via a detailed understanding of the dynamics of nuclear spins during the NMR pulse sequences. I notably developed advanced NMR experiments to probe the local environments of quadrupolar nuclei, such as 27Al, 11B or 17O, which account for over 75% of all NMR-accessible nuclei. These novel techniques have been combined with cutting-edge technologies, including high magnetic fields, dynamic nuclear polarization (DNP, see below) and ultra-fast magic-angle spinning (MAS).

 

 

Representative publications:

DNP of materials

 

Dynamic Nuclear Polarization (DNP), which is based on the microwave-driven polarization transfer from unpaired electrons to surrounding nuclei, has been shown to improve by one to three orders of magnitude the sensitivity of NMR experiments on materials under magic-angle spinning (MAS). I have been among the pioneers of DNP-NMR of materials. I have notably applied this technique to characterize the atomic-level structure of mesoporous materials and nanoparticles.

 

 

Representative publications:

Heterogeneous catalysts and porous materials

 

I have introduced sophisticated NMR methods to characterize heterogeneous catalysts and porous materials, including zeolites, metal-organic frameworks, amorphous silica-alumina and supported catalysts. These solid-state NMR experiments have notably provided key insights into the structure of the active sites and their interaction with reactants.

 

 

Representative publications:

 

Energy materials (battery, photovoltaics)

 

I have also employed solid-state NMR to probe the atomic-level structure of energy materials, including solid electrolytes and cathode materials for Li-ion batteries as well as hybrid perovskite-based photovoltaics.

 

 

Representative publications:

Positions:

2011

Professor (professeur) with 1st class since 2018, head of research group

UCCS, Dept. of Chemistry, Univ. of Lille, France
2015

Visiting professor

Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, China
2007 - 2011

Assistant professor (maître de conférences)

ENSCL (one of the French Grandes Ecoles of Chemistry), France
2006 - 2007

Postdoctoral researcher

Iramis/NIMBE, Atomic Energy Commission (CEA), France

Education:

2017

Young leaders program of Institut de l’entreprise, a think tank of French companies
2010

Habilitation, highest degree in French universities, mandatory to supervise PhD students

Dept. of Chemistry, Univ. of Lille, France
2006

PhD, ICMMO, Dept. of Chemistry, Univ. of Paris-Saclay, France
2003

MSc (1st rank), ICMMO, Dept. of Chemistry, Univ. of Paris-Saclay, France
2002

BSc and agrégation (a highly selective competitive examination to recruit teachers)

Department of Physical Science, Ecole Normale Superieure (ENS) Lyon, France

Institutional responsabilities:

2017 -

Responsible of the transnational access to spectroscopy within the EUSMI European infrastructure (H2020-INFRAIA)
2015 -

Scientific coordinator of 1.2 GHz NMR CPER project (15 M€: equipment + building).
2015 -

Industrial liaison officer, IR-RMN infrastructure/ France.
2015 -

Chief science officer, Lille high-field NMR facility in the IR-RMN infrastructure/ France
2008 -

Member of search committees, University of Nantes and ENSCL/France

Editing and review activities

2017 Member of editorial board and special editor of an issue about the solid-state NMR of quadrupolar nuclei, Solid-State Nuclear Magnetic Resonance
2016, 2019

Review member of chemistry panel, ANR (French research funding agency), France

 

  • Reviewer, Horizon 2020 (EU), US Department of Energy and NHMFL (USA), EPSRC (UK), GDCh (Germany), Swiss Academy of Engineering Sciences (Switzerland), FNRS and FWO (Belgium), TIFR (India), ANR (France), Atomic Energy Commission (CEA) (France), Research division of Ile-de-France State (France), CNRS (France), University of Paris-South (France)
  • Reviewer for several scientific journals (Chem. Sci., J. Am. Chem. Soc., ACS Omega, J. Phys. Chem. C, PCCP, Nano Lett., ChemCatChem, J. Cat…)

Organisation of scientific meetings

Organization committee (OC), scientific committee (SC)

 

2014, 2021 Chair of OC and SC of NMR and industry meeting (130 participants) in Paris/France
2021 Member of the OC of HYP20 conference (130 participants expected) in Lyon/France
2019 Chair of the OC and SC of 11th user meeting of IR-RMN (130 participants) in Villeneuve d’Ascq/France
2018 Chair of the OC and SC of “Ultra-high field NMR spectroscopy: challenges and new horizons” (113 participants) in Villeneuve d’Ascq/France
2018 Vice-chair of the OC and member of the SC of EUROMAR (723 participants, largest European conference about magnetic resonance) in Nantes/France
2017 Chair of the OC and SC of “Catalysis by Design Using NMR” symposium (100 participants) Lille/France

Teaching activities

2011 - Professor – Chemistry, Univ. of Lille/France. Half-time research/half-time teaching (reduced teaching load since 2016 and appointment to IUF). I coordinate a MOOC in NMR since 2014. I also created courses in NMR spectroscopy, notably in the Erasmus Mundus MSc in Advanced Spectroscopy in Chemistry.
2017 - Creation of a stand on NMR within Xperium showcase of the Univ. of Lille, which welcomes high-school students, their teachers and companies
2010 - Lectures on SSNMR in summer schools held in Oppurg (Germany) in 2010, Mexico City in 2011, Bogota (Colombia) in 2018, Villeneuve d’Ascq (2011, 2019), online (2020)
2006 - 2011 Assistant professor – Chemistry, ENSCL/France (physics)
2003 - 2006 Teaching assistant – Chemistry, Univ. of Paris-Saclay/France.

Publications

Publications in the database: 105 (since 2008)

  • 2023

  • Examining a Year-Long Chemical Degradation Process and Reaction Kinetics in Pristine and Defect-Passivated Lead Halide Perovskites.
    Raval Parth, Akhavan Kazemi Mohammad Ali, Ruellou Julie, Trébosc Julien, Lafon Olivier, Delevoye Laurent, Sauvage Frédéric, Manjunatha Reddy G. N.
    Chemistry of Materials, vol. 35, pg. 2904-2917 (2023) DOI
     
  • Boron Adsorption Kinetics of Microcrystalline Cellulose and Polymer Resin.
    Raval Parth, Thomas Neethu, Hamdouna Lama, Delevoye Laurent, Lafon Olivier, Manjunatha Reddy G. N.
    Langmuir, vol. 39, pg. 5384-5395 (2023) DOI
     

  • 2022

  • Probing adsorption of water and DMF in UiO-66(Zr) using solid-state NMR.
    Venel Florian, Volkringer Christophe, Lafon Olivier, Pourpoint Frédérique.
    Solid State Nuclear Magnetic Resonance, vol. 120, pg. 101797 (2022) DOI
     

  • 2021

  • B2O3-Doped LATP Glass-Ceramics Studied by X-ray Diffractometry and MAS NMR Spectroscopy Methods.
    Ślubowska Wioleta, Montagne Lionel, Lafon Olivier, Méar François, Kwatek Konrad.
    Nanomaterials, vol. 11, pg. 390 (2021) DOI
     

  • 2020

  • Structural and electrical properties of ceramic Li-ion conductors based on Li1.3Al0.3Ti1.7(PO4)3-LiF.
    Kwatek K., Ślubowska W., Trébosc J., Lafon O., Nowiński J.L.
    Journal of the European Ceramic Society, vol. 40, pg. 85-93 (2020) DOI
     
  • Multinuclear NMR in polypeptide liquid crystals: Three fertile decades of methodological developments and analytical challenges.
    Lesot Philippe, Aroulanda Christie, Berdagué Philippe, Meddour Abdelkrim, Merlet Denis, Farjon Jonathan, Giraud Nicolas, Lafon Olivier.
    Progress in Nuclear Magnetic Resonance Spectroscopy, vol. 116, pg. 85-154 (2020) DOI
     
  • Quantification of the amount of mobile components in intact stratum corneum with natural-abundance 13C solid-state NMR.
    Pham Quoc Dat, Carlström Göran, Lafon Olivier, Sparr Emma, Topgaard Daniel.
    Physical Chemistry Chemical Physics, vol. 22, pg. 6572-6583 (2020) DOI
     
  • Impact of Li2.9B0.9S0.1O3.1 glass additive on the structure and electrical properties of the LATP-based ceramics.
    Kwatek K., Ślubowska W., Trébosc J., Lafon O., Nowiński J.L.
    Journal of Alloys and Compounds, vol. 820, pg. 153072 (2020) DOI
     
  • Acidity enhancement through synergy of penta- and tetra-coordinated aluminum species in amorphous silica networks.
    Wang Zichun, Li Tong, Jiang Yijiao, Lafon Olivier, Liu Zongwen, Trébosc Julien, Baiker Alfons, Amoureux Jean-Paul, Huang Jun.
    Nature Communications, vol. 11 (2020) DOI
     
  • Observation of Low-γ Quadrupolar Nuclei by Surface-Enhanced NMR Spectroscopy.
    Nagashima Hiroki, Trébosc Julien, Kon Yoshihiro, Sato Kazuhiko, Lafon Olivier, Amoureux Jean-Paul.
    Journal of the American Chemical Society, vol. 142, pg. 10659-10672 (2020) DOI
     
  • gem ‐Diol‐Type Intermediate in the Activation of a Ketone on Sn‐β Zeolite as Studied by Solid‐State NMR Spectroscopy .
    Qi Guodong, Chu Yueying, Wang Qiang, Wang Xingxing, Li Yi, Trébosc Julien, Lafon Olivier, Xu Jun, Deng Feng.
    Angewandte Chemie International Edition, (2020) DOI
     
  • Anionic redox reactions and structural degradation in a cation-disordered rock-salt Li1.2Ti0.4Mn0.4O2 cathode material revealed by solid-state NMR and EPR.
    Geng Fushan, Hu Bei, Li Chao, Zhao Chong, Lafon Olivier, Trébosc Julien, Amoureux Jean-Paul, Shen Ming, Hu Bingwen.
    Journal of Materials Chemistry A, vol. 8, pg. 16515-16526 (2020) DOI
     
  • Recent Advances of Solid‐State NMR Spectroscopy for Microporous Materials.
    Li Shenhui, Lafon Olivier, Wang Weiyu, Wang Qiang, Wang Xingxing, Li Yi, Xu Jun, Deng Feng.
    Advanced Materials, pg. 2002879 (2020) DOI
     
  • Defect Passivation via the Incorporation of Tetrapropylammonium Cation Leading to Stability Enhancement in Lead Halide Perovskite.
    Krishna Anurag, Akhavan Kazemi Mohammad Ali, Sliwa Michel, Reddy G. N. Manjunatha, Delevoye Laurent, Lafon Olivier, Felten Alexandre, Do Mai Trang, Gottis Sébastien, Sauvage Frédéric.
    Advanced Functional Materials, vol. 30, pg. 1909737 (2020) DOI
     
  • Probing Functionalities and Acidity of Calcined Phenylene-Bridged Periodic Mesoporous Organosilicates Using Dynamic Nuclear Polarization NMR, Diffuse Reflectance Infrared Fourier Transform Spectroscopy, and X-ray Photoelectron Spectroscopy.
    Pirez Cyril, Nagashima Hiroki, Dumeignil Franck, Lafon Olivier.
    The Journal of Physical Chemistry C, vol. 124, pg. 6110-6120 (2020) DOI
     

  • 2019

  • Magnetization transfer from protons to quadrupolar nuclei in solid-state NMR using PRESTO or dipolar-mediated refocused INEPT methods.
    Giovine Raynald, Trébosc Julien, Pourpoint Frédérique, Lafon Olivier, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 299, pg. 109-123 (2019) DOI
     
  • Properties of LiMnBO3 glasses and nanostructured glass-ceramics.
    Michalski Przemysław P., Gołębiewska Agata, Trébosc Julien, Lafon Olivier, Pietrzak Tomasz K., Ryl Jacek, Nowiński Jan L., Wasiucionek Marek, Garbarczyk Jerzy E.
    Solid State Ionics, vol. 334, pg. 88-94 (2019) DOI
     
  • Analysis of HMQC experiments applied to a spin ½ nucleus subject to very large CSA.
    Paluch Piotr, Rankin Andrew G.M., Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul.
    Solid State Nuclear Magnetic Resonance, vol. 100, pg. 11-25 (2019) DOI
     
  • Improved sensitivity and quantification for 29Si NMR experiments on solids using UDEFT (Uniform Driven Equilibrium Fourier Transform).
    Duong Nghia Tuan, Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul.
    Solid State Nuclear Magnetic Resonance, vol. 100, pg. 52-62 (2019) DOI
     
  • Evaluation of excitation schemes for indirect detection of 14N via solid-state HMQC NMR experiments.
    Rankin Andrew G.M., Trébosc Julien, Paluch Piotr, Lafon Olivier, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 303, pg. 28-41 (2019) DOI
     
  • Hadamard acquisition of 13 C-13 C 2-D correlation NMR spectra.
    Paluch Piotr, Kupče Ēriks, Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul.
    Magnetic Resonance in Chemistry, (2019) DOI
     
  • The acidic nature of “NMR-invisible” tri-coordinated framework aluminum species in zeolites.
    Xin Shaohui, Wang Qiang, Xu Jun, Chu Yueying, Wang Pengfei, Feng Ningdong, Qi Guodong, Trébosc Julien, Lafon Olivier, Fan Weibin, Deng Feng.
    Chemical Science, vol. 10, pg. 10159-10169 (2019) DOI
     
  • Recent developments in MAS DNP-NMR of materials.
    Rankin Andrew G.M., Trébosc Julien, Pourpoint Frédérique, Amoureux Jean-Paul, Lafon Olivier.
    Solid State Nuclear Magnetic Resonance, vol. 101, pg. 116-143 (2019) DOI
     

  • 2018

  • Recording 13C-15N HMQC 2D sparse spectra in solids in 30 s.
    Kupče Ēriks, Trébosc Julien, Perrone Barbara, Lafon Olivier, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 288, pg. 76-83 (2018) DOI
     
  • Uniform signal enhancement in MAS NMR of half-integer quadrupolar nuclei using quadruple-frequency sweeps.
    Wang Qiang, Trébosc Julien, Li Yixuan, Lafon Oliver, Xin Shaohui, Xu Jun, Hu Bingwen, Feng Ningdong, Amoureux Jean-Paul, Deng Feng.
    Journal of Magnetic Resonance, vol. 293, pg. 92-103 (2018) DOI
     
  • Indirect detection of broad spectra in solid-state NMR using interleaved DANTE trains.
    Li Yixuan, Trébosc Julien, Hu Bingwen, Shen Ming, Amoureux Jean-Paul, Lafon Olivier.
    Journal of Magnetic Resonance, vol. 294, pg. 101-114 (2018) DOI
     
  • 14N overtone nuclear magnetic resonance of rotating solids.
    Gan Zhehong, Hung Ivan, Nishiyama Yusuke, Amoureux Jean-Paul, Lafon Olivier, Nagashima Hiroki, Trébosc Julien, Hu Bingwen.
    The Journal of Chemical Physics, vol. 149, pg. 064201 (2018) DOI
     
  • Simple and Robust Study of Backbone Dynamics of Crystalline Proteins Employing 1H–15N Dipolar Coupling Dispersion.
    Paluch Piotr, Pawlak Tomasz, Ławniczak Karol, Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul, Potrzebowski Marek J.
    The Journal of Physical Chemistry B, vol. 122, pg. 8146-8156 (2018) DOI
     
  • The Surprising Stability of Cu3(btc)2 Metal–Organic Framework under Steam Flow at High Temperature.
    Giovine Raynald, Pourpoint Frédérique, Duval Sylvain, Lafon Olivier, Amoureux Jean-Paul, Loiseau Thierry, Volkringer Christophe.
    Crystal Growth < Design, vol. 18, pg. 6681-6693 (2018) DOI
     
  • Observation of proximities between spin-1/2 and quadrupolar nuclei in solids: Improved robustness to chemical shielding using adiabatic symmetry-based recoupling.
    Nagashima Hiroki, Lilly Thankamony Aany Sofia, Trébosc Julien, Montagne Lionel, Kerven Gwendal, Amoureux Jean-Paul, Lafon Olivier.
    Solid State Nuclear Magnetic Resonance, vol. 94, pg. 7-19 (2018) DOI
     

  • 2017

  • Jean-Paul Amoureux: Having fun with quadrupolar nuclei.
    Lafon Olivier.
    Solid State Nuclear Magnetic Resonance, vol. 84, pg. 1-3 (2017) DOI
     
  • Probing the aluminum complexation by Siberian riverine organic matter using solid-state DNP-NMR.
    Pourpoint Frédérique, Templier Joëlle, Anquetil Christelle, Vezin Hervé, Trébosc Julien, Trivelli Xavier, Chabaux François, Pokrovsky Oleg S., Prokushkin Anatoly S., Amoureux Jean-Paul, Lafon Olivier, Derenne Sylvie.
    Chemical Geology, vol. 452, pg. 1-8 (2017) DOI
     
  • Local measure of the electromagnetic field in magnetic resonance coils: How do simulations help to disentangle the contributions of the electric and magnetic fields?.
    Dillmann Baudouin, Dubois Luc, Paleczny Erick, Trébosc Julien, Amoureux Jean-Paul, Pourpoint Frédérique, Lafon Olivier.
    Solid State Nuclear Magnetic Resonance, vol. 82-83, pg. 1-9 (2017) DOI
     
  • 3D correlation NMR spectrum between three distinct heteronuclei for the characterization of inorganic samples: Application on sodium alumino-phosphate materials.
    Nagashima Hiroki, Tricot Grégory, Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul, Pourpoint Frédérique.
    Solid State Nuclear Magnetic Resonance, vol. 84, pg. 164-170 (2017) DOI
     
  • 71 Ga- 77 Se connectivities and proximities in gallium selenide crystal and glass probed by solid-state NMR.
    Nagashima Hiroki, Trébosc Julien, Calvez Laurent, Pourpoint Frédérique, Mear François, Lafon Olivier, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 282, pg. 71-82 (2017) DOI
     
  • Imaging the spatial distribution of radiofrequency field, sample and temperature in MAS NMR rotor.
    Nagashima Hiroki, Trébosc Julien, Lafon Olivier, Pourpoint Frédérique, Paluch Piotr, Potrzebowski Marek J., Amoureux Jean-Paul.
    Solid State Nuclear Magnetic Resonance, vol. 87, pg. 137-142 (2017) DOI
     
  • Minimizing the t 1 -noise when using an indirect 1 H high-resolution detection of unlabeled samples.
    Shen M., Wegner S., Trébosc J., Hu B., Lafon O., Amoureux J.P.
    Solid State Nuclear Magnetic Resonance, vol. 87, pg. 111-116 (2017) DOI
     
  • Study of Xenon Mobility in the Two Forms of MIL-53(Al) Using Solid-State NMR Spectroscopy.
    Giovine Raynald, Volkringer Christophe, Springuel-Huet Marie-Anne, Nossov Andrei, Blanc Frédéric, Trébosc Julien, Loiseau Thierry, Amoureux Jean-Paul, Lafon Olivier, Pourpoint Frédérique.
    The Journal of Physical Chemistry C, vol. 121, pg. 19262-19268 (2017) DOI
     
  • Solid-State NMR Spectroscopy Proves the Presence of Penta-coordinated Sc Sites in MIL-100(Sc).
    Giovine Raynald, Volkringer Christophe, Ashbrook Sharon E., Trébosc Julien, McKay David, Loiseau Thierry, Amoureux Jean-Paul, Lafon Olivier, Pourpoint Frédérique.
    Chemistry - A European Journal, vol. 23, pg. 9525-9534 (2017) DOI
     
  • NMR crystallography to probe the breathing effect of the MIL-53(Al) metal–organic framework using solid-state NMR measurements of 13C–27Al distances.
    Giovine Raynald, Volkringer Christophe, Trébosc Julien, Amoureux Jean-Paul, Loiseau Thierry, Lafon Olivier, Pourpoint Frédérique.
    Acta Crystallographica Section C Structural Chemistry, vol. 73, pg. 176-183 (2017) DOI
     

  • 2016

  • Synergic Effect of Active Sites in Zinc-Modified ZSM-5 Zeolites as Revealed by High-Field Solid-State NMR Spectroscopy.
    Qi Guodong, Wang Qiang, Xu Jun, Trébosc Julien, Lafon Olivier, Wang Chao, Amoureux Jean-Paul, Deng Feng.
    Angewandte Chemie International Edition, vol. 55, pg. 15826-15830 (2016) DOI
     
  • Brønsted acid sites based on penta-coordinated aluminum species.
    Wang Zichun, Jiang Yijiao, Lafon Olivier, Trébosc Julien, Duk Kim Kyung, Stampfl Catherine, Baiker Alfons, Amoureux Jean-Paul, Huang Jun.
    Nature Communications, vol. 7, pg. 13820 (2016) DOI
     
  • Stability of metal–organic frameworks under gamma irradiation.
    Volkringer C., Falaise C., Devaux P., Giovine R., Stevenson V., Pourpoint F., Lafon O., Osmond M., Jeanjacques C., Marcillaud B., Sabroux J. C., Loiseau T.
    Chemical Communications, vol. 52, pg. 12502-12505 (2016) DOI
     

  • 2015

  • NMR and EPR Characterization of Functionalized Nanodiamonds.
    Presti Charlène, Thankamony Aany S. Lilly, Alauzun Johan G., Mutin P. Hubert, Carnevale Diego, Lion Cédric, Vezin Hervé, Laurencin Danielle, Lafon Olivier.
    The Journal of Physical Chemistry C, vol. 119, pg. 12408-12422 (2015) DOI
     
  • Observation of 1H–13C and 1H–1H proximities in a paramagnetic solid by NMR at high magnetic field under ultra-fast MAS.
    Li Shenhui, Trébosc Julien, Lafon Olivier, Zhou Lei, Shen Ming, Pourpoint Frédérique, Amoureux Jean-Paul, Deng Feng.
    Journal of Magnetic Resonance, vol. 251, pg. 36-42 (2015) DOI
     
  • Population transfer HMQC for half-integer quadrupolar nuclei.
    Wang Qiang, Li Yixuan, Trébosc Julien, Lafon Olivier, Xu Jun, Hu Bingwen, Feng Ningdong, Chen Qun, Amoureux Jean-Paul, Deng Feng.
    The Journal of Chemical Physics, vol. 142, pg. 094201 (2015) DOI
     
  • NMR Crystallography of an Oxovanadium(V) Complex by an Approach Combining Multinuclear Magic Angle Spinning NMR, DFT, and Spin Dynamics Simulations.
    Pourpoint Frédérique, Yehl Jenna, Li Mingyue, Gupta Rupal, Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul, Polenova Tatyana.
    ChemPhysChem, vol. 16, pg. 1619-1626 (2015) DOI
     
  • Comparison of various NMR methods for the indirect detection of nitrogen-14 nuclei via protons in solids.
    Shen Ming, Trébosc Julien, O’Dell Luke A., Lafon Olivier, Pourpoint Frédérique, Hu Bingwen, Chen Qun, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 258, pg. 86-95 (2015) DOI
     
  • Solid-state NMR indirect detection of nuclei experiencing large anisotropic interactions using spinning sideband-selective pulses.
    Shen Ming, Trébosc Julien, Lafon Olivier, Gan Zhehong, Pourpoint Frédérique, Hu Bingwen, Chen Qun, Amoureux Jean-Paul.
    Solid State Nuclear Magnetic Resonance, vol. 72, pg. 104-117 (2015) DOI
     
  • Fast acquisition of multidimensional NMR spectra of solids and mesophases using alternative sampling methods.
    Lesot Philippe, Kazimierczuk Krzysztof, Trébosc Julien, Amoureux Jean-Paul, Lafon Olivier.
    Magnetic Resonance in Chemistry, vol. 53, pg. 927-939 (2015) DOI
     
  • Insights into the Catalytic Activity of Nitridated Fibrous Silica (KCC-1) Nanocatalysts from15N and29Si NMR Spectroscopy Enhanced by Dynamic Nuclear Polarization.
    Lilly Thankamony Aany Sofia, Lion Cédric, Pourpoint Frédérique, Singh Baljeet, Perez Linde Angel J., Carnevale Diego, Bodenhausen Geoffrey, Vezin Hervé, Lafon Olivier, Polshettiwar Vivek.
    Angewandte Chemie International Edition, vol. 54, pg. 2190-2193 (2015) DOI
     

  • 2014

  • Host–Guest Interactions in Dealuminated HY Zeolite Probed by13C–27Al Solid-State NMR Spectroscopy.
    Li Shenhui, Pourpoint Frédérique, Trébosc Julien, Zhou Lei, Lafon Olivier, Shen Ming, Zheng Anmin, Wang Qiang, Amoureux Jean-Paul, Deng Feng.
    The Journal of Physical Chemistry Letters, vol. 5, pg. 3068-3072 (2014) DOI
     
  • Probing 27Al–13C proximities in metal–organic frameworks using dynamic nuclear polarization enhanced NMR spectroscopy.
    Pourpoint Frédérique, Thankamony Aany Sofia Lilly, Volkringer Christophe, Loiseau Thierry, Trébosc Julien, Aussenac Fabien, Carnevale Diego, Bodenhausen Geoffrey, Vezin Hervé, Lafon Olivier, Amoureux Jean-Paul.
    Chemical Communications, vol. 50, pg. 933 (2014) DOI
     
  • Correlation 2D-NMR experiments involving both13C and2H isotopes in oriented media: methodological developments and analytical applications.
    Lesot Philippe, Lafon Olivier, Berdagué Philippe.
    Magnetic Resonance in Chemistry, vol. 52, pg. 595-613 (2014) DOI
     
  • Improving the resolution in proton-detected through-space heteronuclear multiple quantum correlation NMR spectroscopy.
    Shen Ming, Trébosc J., Lafon O., Pourpoint F., Hu Bingwen, Chen Qun, Amoureux J.-P.
    Journal of Magnetic Resonance, vol. 245, pg. 38-49 (2014) DOI
     
  • Primostrato Solid-State NMR Enhanced by Dynamic Nuclear Polarization: Pentacoordinated Al3+Ions Are Only Located at the Surface of Hydrated γ-Alumina.
    Lee Daniel, Duong Nghia Tuan, Lafon Olivier, De Paëpe Gaël.
    The Journal of Physical Chemistry C, vol. 118, pg. 25065-25076 (2014) DOI
     
  • Criteria for sensitivity enhancement by compressed sensing: practical application to anisotropic NAD 2D-NMR spectroscopy.
    Kazimierczuk Krzysztof, Lafon Olivier, Lesot Philippe.
    The Analyst, vol. 139, pg. 2702 (2014) DOI
     
  • Quantitative Analysis of the Proximities of OH Ligands and Vanadium Sites in a Polyoxovanadate Cluster Using Frequency-Selective1H–51V Solid-State NMR Spectroscopy.
    Pourpoint Frédérique, Trébosc Julien, Bonhomme Christian, Durupthy Olivier, Steunou Nathalie, Lafon Olivier, Amoureux Jean-Paul.
    The Journal of Physical Chemistry C, vol. 118, pg. 18580-18588 (2014) DOI
     

  • 2013

  • Exploring various modulation-sideband recoupling conditions of SHA+ sequence at fast MAS.
    Shen Ming, Liu Qinghua, Trébosc Julien, Lafon Oliver, Masuda Yuichi, Takegoshi K., Amoureux Jean-Paul, Hu Bingwen, Chen Qun.
    Solid State Nuclear Magnetic Resonance, vol. 55-56, pg. 42-47 (2013) DOI
     
  • Broadband excitation in solid-state NMR using interleaved DANTE pulse trains with N pulses per rotor period.
    Lu Xingyu, Trébosc Julien, Lafon Olivier, Carnevale Diego, Ulzega Simone, Bodenhausen Geoffrey, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 236, pg. 105-116 (2013) DOI
     
  • Probing proximities between different quadrupolar isotopes using multi-pulse cross-polarization.
    Lu Xingyu, Tankamony Aany Sofia Lilly, Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 228, pg. 148-158 (2013) DOI
     
  • Mesoporous Silica Nanoparticles Loaded with Surfactant: Low Temperature Magic Angle Spinning13C and29Si NMR Enhanced by Dynamic Nuclear Polarization.
    Lafon Olivier, Thankamony Aany S. Lilly, Kobayashi Takeshi, Carnevale Diego, Vitzthum Veronika, Slowing Igor I., Kandel Kapil, Vezin Hervé, Amoureux Jean-Paul, Bodenhausen Geoffrey, Pruski Marek.
    The Journal of Physical Chemistry C, vol. 117, pg. 1375-1382 (2013) DOI
     
  • Analysis of sensitivity enhancement by dynamic nuclear polarization in solid-state NMR: a case study of functionalized mesoporous materials.
    Kobayashi Takeshi, Lafon Olivier, Lilly Thankamony Aany S., Slowing Igor I., Kandel Kapil, Carnevale Diego, Vitzthum Veronika, Vezin Hervé, Amoureux Jean-Paul, Bodenhausen Geoffrey, Pruski Marek.
    Physical Chemistry Chemical Physics, vol. 15, pg. 5553 (2013) DOI
     
  • Indirect and direct 29Si dynamic nuclear polarization of dispersed nanoparticles.
    Lafon Olivier, Thankamony Aany Sofia Lilly, Rosay Melanie, Aussenac Fabien, Lu Xingyu, Trébosc Julien, Bout-Roumazeilles Viviane, Vezin Hervé, Amoureux Jean-Paul.
    Chemical Communications, vol. 49, pg. 2864-2866 (2013) DOI
     
  • Comparison of various sampling schemes and accumulation profiles in covariance spectroscopy with exponentially decaying 2D signals.
    Li Yixuan, Hu Bingwen, Chen Qun, Wang Qiang, Zhang Zhengfeng, Yang Jun, Noda Isao, Trébosc Julien, Lafon Oliver, Amoureux Jean-Paul, Deng Feng.
    The Analyst, vol. 138, pg. 2411 (2013) DOI
     
  • An NMR-Driven Crystallography Strategy to Overcome the Computability Limit of Powder Structure Determination: A Layered Aluminophosphate Case.
    Bouchevreau Boris, Martineau Charlotte, Mellot-Draznieks Caroline, Tuel Alain, Suchomel Matthew R., Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul, Taulelle Francis.
    Chemistry - A European Journal, vol. 19, pg. 5009-5013 (2013) DOI
     
  • High-Resolution Structural Characterization of Two Layered Aluminophosphates by Synchrotron Powder Diffraction and NMR Crystallographies.
    Bouchevreau Boris, Martineau Charlotte, Mellot-Draznieks Caroline, Tuel Alain, Suchomel Matthew R., Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul, Taulelle Francis.
    Chemistry of Materials, vol. 25, pg. 2227-2242 (2013) DOI
     
  • Signal enhancement of J-HMQC experiments in solid-state NMR involving half-integer quadrupolar nuclei.
    Wang Qiang, Trébosc Julien, Li Yixuan, Xu Jun, Hu Bingwen, Feng Ningdong, Chen Qun, Lafon Olivier, Amoureux Jean-Paul, Deng Feng.
    Chemical Communications, vol. 49, pg. 6653-6655 (2013) DOI
     
  • Measurement of the shortest hetero-nuclear distances in multiple-spin systems using constant-time correlation NMR methods.
    Amoureux Jean-Paul, Lu Xingyu, Trébosc Julien, Lafon Olivier.
    CrystEngComm, vol. 15(43), pg. 8713-8726 (2013) DOI
     
  • Advances in Structural Studies on Alkylaluminum Species in the Solid State via Challenging27Al–13C NMR Spectroscopy and X-ray Diffraction.
    Pourpoint Frédérique, Morin Yohann, Gauvin Régis M., Trébosc Julien, Capet Frédéric, Lafon Olivier, Amoureux Jean-Paul.
    The Journal of Physical Chemistry C, vol. 117, pg. 18091-18099 (2013) DOI
     

  • 2012

  • Detailed analysis of the S-RESPDOR solid-state NMR method for inter-nuclear distance measurement between spin-1/2 and quadrupolar nuclei.
    Lu Xingyu, Lafon Olivier, Trébosc Julien, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 215, pg. 34-49 (2012) DOI
     
  • High-resolution through-space correlations between spin-1/2 and half-integer quadrupolar nuclei using the MQ-D-R-INEPT NMR experiment.
    Martineau Charlotte, Bouchevreau Boris, Taulelle Francis, Trébosc Julien, Lafon Olivier, Paul Amoureux Jean.
    Physical Chemistry Chemical Physics, vol. 14, pg. 7112 (2012) DOI
     
  • Practical choice of 1H–1H decoupling schemes in through-bond 1H–{X} HMQC experiments at ultra-fast MAS.
    Nishiyama Yusuke, Lu Xingyu, Trébosc Julien, Lafon Olivier, Gan Zhehong, Madhu P.K., Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 214, pg. 151-158 (2012) DOI
     
  • Quantitative cross-polarization at magic-angle spinning frequency of about 20kHz.
    Takeda Kazuyuki, Noda Yasuto, Takegoshi K., Lafon Olivier, Trébosc Julien, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 214, pg. 340-345 (2012) DOI
     
  • Solvent-Free High-Field Dynamic Nuclear Polarization of Mesoporous Silica Functionalized with TEMPO.
    Lilly Thankamony Aany Sofia, Lafon Olivier, Lu Xingyu, Aussenac Fabien, Rosay Melanie, Trébosc Julien, Vezin Hervé, Amoureux Jean-Paul.
    Applied Magnetic Resonance, vol. 43, pg. 237-250 (2012) DOI
     
  • Observation of proximities between spin-1∕2 and quadrupolar nuclei: Which heteronuclear dipolar recoupling method is preferable?.
    Lu X., Lafon O., Trébosc J., Tricot G., Delevoye L., Méar F., Montagne L., Amoureux J. P.
    The Journal of Chemical Physics, vol. 137, pg. 144201 (2012) DOI
     
  • Detailed analysis of the TIMES and TIMES0 high-resolution MAS methods for high-resolution proton NMR.
    Lu Xingyu, Lafon Olivier, Trébosc Julien, Thankamony Aany Sofia Lilly, Nishiyama Yusuke, Gan Zhehong, Madhu P.K., Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 223, pg. 219-227 (2012) DOI
     
  • Very-Long-Distance Correlations in Proteins Revealed by Solid-State NMR Spectroscopy.
    Hu Bingwen, Trébosc Julien, Lafon Oliver, Chen Qun, Masuda Yuichi, Takegoshi K., Amoureux Jean-Paul.
    ChemPhysChem, vol. 13, pg. 3585-3588 (2012) DOI
     
  • Uniform broadband excitation of crystallites in rotating solids using interleaved sequences of delays alternating with nutation.
    Vitzthum Veronika, Caporini Marc A., Ulzega Simone, Trébosc Julien, Lafon Olivier, Amoureux Jean-Paul, Bodenhausen Geoffrey.
    Journal of Magnetic Resonance, vol. 223, pg. 228-236 (2012) DOI
     
  • Broadband excitation in solid-state NMR of paramagnetic samples using Delays Alternating with Nutation for Tailored Excitation (‘Para-DANTE’).
    Carnevale Diego, Vitzthum Veronika, Lafon Olivier, Trébosc Julien, Amoureux Jean-Paul, Bodenhausen Geoffrey.
    Chemical Physics Letters, vol. 553, pg. 68-76 (2012) DOI
     
  • Measurement of Aluminum-Carbon Distances Using S-RESPDOR NMR Experiments.
    Pourpoint Frédérique, Trébosc Julien, Gauvin Régis M., Wang Qiang, Lafon Olivier, Deng Feng, Amoureux Jean-Paul.
    ChemPhysChem, vol. 13, pg. 3605-3615 (2012) DOI
     
  • Enhanced 2D solid-state NMR correlation spectroscopy of quadrupolar nuclei using dynamic nuclear polarization.
    Lee D, Takahashi H, Thankamony A S Lilly, Dacquin J -Ph, Bardet M, Lafon O, Paëpe G De.
    Journal of the American Chemical Society, vol. 134, pg. 18491 (2012) DOI
     
  • Broadband finite-pulse radio-frequency-driven recoupling (fp-RFDR) with (XY8)41 super-cycling for homo-nuclear correlations in very high magnetic fields at fast and ultra-fast MAS frequencies.
    Shen Ming, Hu Bingwen, Lafon Oliver, Trébosc Julien, Chen Qun, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 223, pg. 107-119 (2012) DOI
     

  • 2011

  • A tunable homonuclear dipolar decoupling scheme for high-resolution proton NMR of solids from slow to fast magic-angle spinning.
    Gan Zhehong, Madhu P.K., Amoureux Jean-Paul, Trébosc Julien, Lafon Olivier.
    Chemical Physics Letters, vol. 503, pg. 167-170 (2011) DOI
     
  • Broad-band homo-nuclear correlations assisted by 1H irradiation for bio-molecules in very high magnetic field at fast and ultra-fast MAS frequencies.
    Hu Bingwen, Lafon Oliver, Trébosc Julien, Chen Qun, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 212, pg. 320-329 (2011) DOI
     
  • Fast and High-Resolution Stereochemical Analysis by Nonuniform Sampling and Covariance Processing of Anisotropic Natural Abundance 2D 2H NMR Datasets.
    Lafon Olivier, Hu Bingwen, Amoureux Jean-Paul, Lesot Philippe.
    Chemistry - A European Journal, vol. 17, pg. 6716-6724 (2011) DOI
     
  • Beyond the Silica Surface by Direct Silicon-29 Dynamic Nuclear Polarization.
    Lafon Olivier, Rosay Melanie, Aussenac Fabien, Lu Xingyu, Trébosc Julien, Cristini Odile, Kinowski Christophe, Touati Nadia, Vezin Hervé, Amoureux Jean-Paul.
    Angewandte Chemie International Edition, vol. 50, pg. 8367-8370 (2011) DOI
     
  • Observing 13C–13C connectivities at high magnetic fields and very high spinning frequencies.
    Lafon Olivier, Trébosc Julien, Hu Bingwen, Paëpe Gaël De, Amoureux Jean-Paul.
    Chemical Communications, vol. 47, pg. 6930 (2011) DOI
     
  • Rotor-synchronized dipolar-filter sequence at fast MAS in solid-state NMR.
    Liu Qing-Hua, Ma Chao, Hu Bing-Wen, Chen Qun, Trebosc Julien, Lafon Olivier, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 212, pg. 455-459 (2011) DOI
     
  • Structural characterisation of phosphate materials: new insights into the spatial proximities between phosphorus and quadrupolar nuclei using the D-HMQC MAS NMR technique.
    Tricot G., Lafon O., Trébosc J., Delevoye L., Méar F., Montagne L., Amoureux J-P.
    Physical Chemistry Chemical Physics, vol. 13, pg. 16786 (2011) DOI
     
  • Measurement of 13C–1H dipolar couplings in solids by using ultra-fast magic-angle spinning NMR spectroscopy with symmetry-based sequences.
    Wang Qiang, Lu Xingyu, Lafon Olivier, Trébosc Julien, Deng Feng, Hu Bingwen, Chen Qun, Amoureux Jean-Paul.
    Physical Chemistry Chemical Physics, vol. 13, pg. 5967 (2011) DOI
     

  • 2010

  • Distance measurement between a spin-1/2 and a half-integer quadrupolar nuclei by solid-state NMR using exact analytical expressions.
    Chen Lei, Lu Xingyu, Wang Qiang, Lafon Olivier, Trébosc Julien, Deng Feng, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 206, pg. 269-273 (2010) DOI
     
  • Measurement of hetero-nuclear distances using a symmetry-based pulse sequence in solid-state NMR.
    Chen Lei, Wang Qiang, Hu Bingwen, Lafon Olivier, Trébosc Julien, Deng Feng, Amoureux Jean-Paul.
    Physical Chemistry Chemical Physics, vol. 12, pg. 9395 (2010) DOI
     
  • Indirect high-resolution detection for quadrupolar spin-3/2 nuclei in dipolar HMQC solid-state NMR experiments.
    Trébosc Julien, Lafon Olivier, Hu Bingwen, Amoureux Jean-Paul.
    Chemical Physics Letters, vol. 496, pg. 201-207 (2010) DOI
     
  • Homonuclear dipolar recoupling under ultra-fast magic-angle spinning: Probing 19F−19F proximities by solid-state NMR.
    Wang Qiang, Hu Bingwen, Lafon Olivier, Trébosc Julien, Deng Feng, Amoureux Jean-Paul.
    Journal of Magnetic Resonance, vol. 203, pg. 113-128 (2010) DOI
     

  • 2009

  • Double-quantum 19F–19F dipolar recoupling at ultra-fast magic angle spinning NMR: application to the assignment of 19F NMR spectra of inorganic fluorides.
    Wang Qiang, Hu Bingwen, Fayon Franck, Trébosc Julien, Legein Christophe, Lafon Olivier, Deng Feng, Amoureux Jean-Paul.
    Physical Chemistry Chemical Physics, vol. 11, pg. 10391 (2009) DOI
     
  • Double-quantum homonuclear NMR correlation spectroscopy of quadrupolar nuclei subjected to magic-angle spinning and high magnetic field.
    Wang Q., Hu B., Lafon O., Trébosc J., Deng F., Amoureux J.P.
    Journal of Magnetic Resonance, vol. 200, pg. 251-260 (2009) DOI
     
  • Double-quantum NMR spectroscopy of 31P species submitted to very large CSAs.
    Hu B., Delevoye L., Lafon O., Trébosc J., Amoureux J.P.
    Journal of Magnetic Resonance, vol. 200, pg. 178-188 (2009) DOI
     
  • Indirect Detection via Spin-1/2 Nuclei in Solid State NMR Spectroscopy: Application to the Observation of Proximities between Protons and Quadrupolar Nuclei.
    Lafon Olivier, Wang Qiang, Hu Bingwen, Vasconcelos Filipe, Trébosc Julien, Cristol Sylvain, Deng Feng, Amoureux Jean-Paul.
    The Journal of Physical Chemistry A, vol. 113, pg. 12864-12878 (2009) DOI
     
  • Proton-proton homonuclear dipolar decoupling in solid-state NMR using rotor-synchronized z-rotation pulse sequences.
    Lafon Olivier, Wang Qiang, Hu Bingwen, Trébosc Julien, Deng Feng, Amoureux Jean-Paul.
    The Journal of Chemical Physics, vol. 130, pg. 014504 (2009) DOI
     
  • Correlation NMR spectroscopy involving quadrupolar nuclei.
    Amoureux J.P., Trébosc J., Delevoye L., Lafon O., Hu B., Wang Q.
    Solid State Nuclear Magnetic Resonance, vol. 35, pg. 12-18 (2009) DOI
     
  • Robust and efficient spin-locked symmetry-based double-quantum homonuclear dipolar recoupling for probing 1H–1H proximity in the solid-state.
    Hu B., Wang Q., Lafon O., Trébosc J., Deng F., Amoureux J.P.
    Journal of Magnetic Resonance, vol. 198, pg. 41-48 (2009) DOI
     
  • Homonuclear dipolar decoupling schemes for fast MAS.
    Amoureux Jean-Paul, Hu Bingwen, Trébosc Julien, Wang Qiang, Lafon Olivier, Deng Feng.
    Solid State Nuclear Magnetic Resonance, vol. 35, pg. 19-24 (2009) DOI
     
  • Enantiodiscrimination of Flexible Cyclic Solutes Using NMR Spectroscopy in Polypeptide Chiral Mesophases: Investigation ofcis-Decalin and THF.
    Aroulanda Christie, Lafon Olivier, Lesot Philippe.
    The Journal of Physical Chemistry B, vol. 113, pg. 10628-10640 (2009) DOI
     

  • 2008

  • Rapid analysis of isotopically unmodified amino acids by high-resolution 14N-edited 1H–13C correlation NMR spectroscopy.
    Amoureux Jean-Paul, Wang Qiang, Hu Bingwen, Lafon Olivier, Trébosc Julien, Deng Feng.
    Chemical Communications, pg. 6525 (2008) DOI
     

 

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