Thèmes de recherche
- Développement des applications de nouvelles techniques d’analyse de surface (XPS, ToF SIMS & LEIS) pour l’étude de la réactivité des surfaces
Recherches actuelles
Depuis ma nomination en novembre 2007, ma thématique de recherche s’est orientée vers la caractérisation de réactivité de surfaces par XPS. Je suis intéressée par la mise en place d’étude de surfaces modèles de catalyseurs. Dans ce cadre, j’ai participé à une demande de financement au projet européen transfrontalier INTERREG IV, en collaboration avec Materia Nova (Belgique) et l’Université de Mons-Hainaut. Notre projet commun porte sur les caractérisations et synthèses de surfaces modèles de catalyseurs (phase métallique) déposés sur des surfaces modèles d’oxydes (de type alumine, silice, titane) qui seront préparées par Materia Nova par dépôts par plasma froid ou PVD sur support conducteur. En plus de la caractérisation, je participerai à la synthèse de films minces d’oxydes de métaux de transition par spin coating.
Parcours de recherche
Depuis novembre 2007
Maître de Conférences à l’ENSCL, chercheur dans l’équipe « Modélisation et Spectroscopie » de l’UCCS
2004 – 2006 ATER
Equipe « Modélisation et Spectroscopie », UCCS
Mes activités de recherche étaient orientées vers la caractérisation des phases actives et intermédiaires réactionnels par différentes méthodes spectroscopiques, plus particulièrement par XPS quasi in situ et Raman operando. L’étude portait sur l’état de surface de catalyseurs à différentes charges en molybdène supportés sur alumine au cours de l’oxydation du méthanol. L’étude a pu être complétée par spectroscopie RPE/UV-vis operando dans le cadre de l’action CONCORDE au cours de mon séjour au LIKat (Berlin) en collaboration avec Dr Angelika Brückner.
2003 – 2004 Post Doctorat
Unité de Catalyse et Chimie des Matériaux Divisés, Université Catholique de Louvain, Louvain la Neuve, Belgique
Préparation par spin coating de catalyseurs modèles de type films minces cristallins à base d’oxyde de Mo et de molybdates de métaux de transition (Bi, Fe, Ni)
2000 – 2003 Doctorat Structure et dynamique des systèmes réactifs
Equipe « Environnement », UCCS
Phases et sites actifs, intermédiaires réactionnels et espèces adsorbées en catalyse sur particules métalliques : analyses spectroscopiques in situ Application de différentes méthodes spectroscopiques (XPS, IR et Raman), utilisés en conditions in situ, pour la caractérisation de la phase et des sites actifs ainsi que l’identification des espèces adsorbées sur des catalyseurs à base de palladium au cours de la transformation de NO et de sa réaction avec CO.
 Evolution du photopic N 1s et du doublet Pd 3d3/2-5/2 sur 10wt%Pd/Al2O3 : (a) après traitement de réduction sous H2 (500°C, 2h) suivi d’une exposition sous flux NO/He (25°C, 1h) sous différentes pressions partielles de NO, PNO = (b) 0,5 kPa, (c) 1,2 kPa et (d) 5,0 kPa
Bibliographie
Articles
Publications dans la base de données : 54 (depuis 2008)2022- Probing the core and surface composition of nanoalloy to rationalize its selectivity: Study of Ni-Fe/SiO2 catalysts for liquid-phase hydrogenation.
Shi Dichao, Sadier Achraf, Girardon Jean-Sébastien, Mamede Anne-Sophie, Ciotonea Carmen, Marinova Maya, Stievano Lorenzo, Sougrati Moulay T., La Fontaine Camille, Paul Sébastien, Wojcieszak Robert, Marceau Eric.
Chem Catalysis, vol. 2, pg. 1686-1708 (2022)  DOI
2021- Selective adsorption of U(VI) from real mine water using an NH2-functionalized silica packed column.
Huynh Jérémie, Palacio Ruben, Allavena Audrey, Gallard Hervé, Descostes Michael, Mamède Anne-Sophie, Royer Sébastien, Tertre Emmanuel, Batonneau-Gener Isabelle.
Chemical Engineering Journal, vol. 405, pg. 126912 (2021) DOI
- Selective aqueous phase hydrogenation of xylose to xylitol over SiO2-supported Ni and Ni-Fe catalysts: Benefits of promotion by Fe.
Sadier Achraf, Shi Dichao, Mamede Anne-Sophie, Paul Sébastien, Marceau Eric, Wojcieszak Robert.
Applied Catalysis B: Environmental, vol. 298, pg. 120564 (2021) DOI
- Mn- or Cu- substituted LaFeO3-based three-way catalysts: Highlighting different catalytically operating modes of La0.67Fe0.8M0.2O3 (M=Cu, Mn).
Nandi Shreya, Wu Jiang Xiang, Simon Pardis, Nuns Nicolas, Trentesaux Martine, Tougerti Asma, Fonda Emiliano, Girardon Jean-Sébastien, Paul Jean-François, Mamede Anne-Sophie, Berrier Elise.
Applied Catalysis B: Environmental, vol. 296, pg. 120330 (2021) DOI
- La1-x(Sr, Na, K)xMnO3 perovskites for HCHO oxidation: The role of oxygen species on the catalytic mechanism.
Xu Yin, Dhainaut Jérémy, Dacquin Jean-Philippe, Mamede Anne-Sophie, Marinova Maya, Lamonier Jean-François, Vezin Hervé, Zhang Hui, Royer Sébastien.
Applied Catalysis B: Environmental, vol. 287, pg. 119955 (2021) DOI
2020- Mesostructured CMK-3 carbon supported Ni–ZrO2 as catalysts for the hydrodeoxygenation of guaiacol.
López Mónica, Palacio Ruben, Royer Sébastien, Mamede Anne-Sophie, Fernández Jhon J.
Microporous and Mesoporous Materials, vol. 292, pg. 109694 (2020) DOI
- Hydrodeoxygenation of guaiacol into cyclohexane over mesoporous silica supported Ni–ZrO2 catalyst.
López Mónica, Palacio Ruben, Mamede Anne-Sophie, Fernández Jhon Jairo, Royer Sébastien.
Microporous and Mesoporous Materials, vol. 309, pg. 110452 (2020) DOI
- Chemical stability of caesium iodide deposits in air/steam atmosphere.
Obada D., Hijazi H., Paul J.-F., Gasnot L., Grégoire A.-C., Mamede A.-S., Cantrel L.
Journal of Hazardous Materials, pg. 124519 (2020) DOI
- Hierarchical porous ε-MnO2 from perovskite precursor: Application to the formaldehyde total oxidation.
Xu Yin, Dhainaut Jérémy, Rochard Guillaume, Dacquin Jean-Philippe, Mamede Anne-Sophie, Giraudon Jean-Marc, Lamonier Jean-François, Zhang Hui, Royer Sébastien.
Chemical Engineering Journal, vol. 388, pg. 124146 (2020) DOI
- Influence of the strontium content on the performance of La1-xSrxMnO3/Bi1.5Er0.5O3 composite electrodes for low temperature Solid Oxide Fuel Cells.
Pajot Martin, Duffort Victor, Capoen Edouard, Mamede Anne-Sophie, Vannier Rose-Noëlle.
Journal of Power Sources, vol. 450, pg. 227649 (2020) DOI
2019- Co3O4/rGO Catalysts for Oxygen Electrocatalysis: On the Role of the Oxide/Carbon Interaction.
Abidat I., Cazayus E., Loupias L., Morais C., Comminges C., Napporn T. W., Portehault D., Durupthy O., Mamede A-S., Chanéac C., Lamonier J.-F., Habrioux A., Kokoh K. B.
Journal of The Electrochemical Society, vol. 166, pg. H94-H102 (2019) DOI
- Synthesis and multifaceted use of phosphorylated graphene oxide: growth of titanium dioxide clusters, interplay with gold nanoparticles and exfoliated sheets in bioplastics.
Anouar Aicha, Katir Nadia, Mamede Anne-Sophie, Aboulaich Abdelhay, Draoui Khalid, Royer Sébastien, El Kadib Abdelkrim.
Materials Chemistry Frontiers, vol. 3, pg. 242-250 (2019) DOI
2018- CuO/CeO2 catalysts for glycerol selective conversion to lactic acid.
Palacio Ruben, Torres Sebastian, Royer Sébastien, Mamede Anne Sophie, López Diana, Hernández Diana.
Dalton Transactions, vol. 47, pg. 4572-4582 (2018) DOI
- Ruthenium behavior in the reactor cooling system in case of a PWR severe accident.
Ohnet M. N., Leroy O., Mamede A. S.
Journal of Radioanalytical and Nuclear Chemistry, vol. 316, pg. 161-177 (2018) DOI
- LaFeO3
thin films as relevant models for the surface investigation of 3-way catalysts.
Nandi Shreya, Blanck Dimitri, Carlier Thomas, Chambrier Marie-Hélène, Mamede Anne-Sophie, Trentesaux Martine, Simon Pardis, Nuns Nicolas, Roussel Pascal, Ferri Anthony, Paul Jean-Francois, Berrier Elise.
Surface and Interface Analysis, pg. 1-7 (2018) DOI
2017- Effect of the presence of ionic liquid during the NiMoS bulk preparation in the transformation of decanoic acid.
Leyral Géraldine, Brillouet Soizic, Rousseau Julie, Richard Frédéric, Mamede Anne Sophie, Courthéoux Laurence, Pradel Annie, Ribes Michel, Brunet Sylvette.
Applied Catalysis A: General, vol. 532, pg. 120-132 (2017) DOI
- Mixed Ba 1−x La x F 2+x fluoride materials as catalyst for the gas phase fluorination of 2-chloropyridine by HF.
Astruc A., Célérier S., Pavon E., Mamede A.-S., Delevoye L., Brunet S.
Applied Catalysis B: Environmental, vol. 204, pg. 107-118 (2017) DOI
- A Simple and Green Procedure to Prepare Efficient Manganese Oxide Nanopowder for the Low Temperature Removal of Formaldehyde.
Ciotonea Carmen, Averlant Rémy, Rochard Guillaume, Mamede Anne-Sophie, Giraudon Jean-Marc, Alamdari Houshang, Lamonier Jean-François, Royer Sébastien.
ChemCatChem, vol. 9, pg. 2366-2376 (2017) DOI
- Guerbet Reaction over Strontium-Substituted Hydroxyapatite Catalysts Prepared at Various (Ca+Sr)/P Ratios.
Silvester Lishil, Lamonier Jean-François, Lamonier Carole, Capron Mickaël, Vannier Rose-Noëlle, Mamede Anne-Sophie, Dumeignil Franck.
ChemCatChem, vol. 9(12), pg. 2250-2261 (2017) DOI
- In situ Raman spectroscopy evidence of an accessible phase potentially involved in the enhanced activity of La-deficient lanthanum orthoferrite in 3-way catalysis (TWC).
Blanck Dimitri, Schön Anke, Mamede Anne-Sophie, Dujardin Christophe, Dacquin Jean-Philippe, Granger Pascal, Paul Jean-François, Berrier Elise.
Catalysis Today, vol. 283, pg. 151-157 (2017) DOI
- Effect of gradual reduction of graphene oxide on the CO tolerance of supported platinum nanoparticles.
Abidat I., Morais C., Pronier S., Guignard N., Comparot J.D., Canaff C., Napporn T.W., Habrioux A., Mamede A.-S., Lamonier J.-F., Kokoh K.B.
Carbon, vol. 111, pg. 849-858 (2017) DOI
2016- Activity of enzymes immobilized on plasma treated polyester.
Mohamed Arfaoui, Nemeshwaree Behary, Brigitte Mutel, Anne Perwuelz, Kalim Belhacene, Pascal Dhulster, Anne-Sophie Mamede, Rénato Froidevaux.
Journal of Molecular Catalysis B: Enzymatic, vol. 134, pg. 261-272 (2016) DOI
- Facile synthesis of highly dispersed and thermally stable copper-based nanoparticles supported on SBA-15 occluded with P123 surfactant for catalytic applications.
Chirieac Alexandru, Dragoi Brindusa, Ungureanu Adrian, Ciotonea Carmen, Mazilu Irina, Royer Sebastien, Mamede Anne Sophie, Rombi Elisabetta, Ferino Italo, Dumitriu Emil.
Journal of Catalysis, vol. 339, pg. 270-283 (2016) DOI
- Multitechnique characterisation of 304L surface states oxidised at high temperature in steam and air atmospheres.
Mamede Anne-Sophie, Nuns Nicolas, Cristol Anne-Lise, Cantrel Laurent, Souvi Sidi, Cristol Sylvain, Paul Jean-François.
Applied Surface Science, vol. 369, pg. 510-519 (2016) DOI
- Role of Promoters on the Acrolein Ammoxidation Performances of BiMoO x.
Ghalwadkar Ajay, Katryniok Benjamin, Paul Sébastien, Mamede Anne-Sophie, Dumeignil Franck.
Journal of the American Oil Chemists<#039; Society, vol. 93 (1), pg. 431-443 (2016) DOI
- Ethanol reactivity over La1+x FeO3+δ perovskites.
Tesquet Guillaume, Faye Jérémy, Hosoglu Fadime, Mamede Anne-Sophie, Dumeignil Franck, Capron Mickaël.
Applied Catalysis A: General, vol. 511, pg. 141-148 (2016) DOI
2015- Electrochemical Characterization and Quantified Surface Termination Obtained by Low Energy Ion Scattering and X-ray Photoelectron Spectroscopy of Orthorhombic and Rhombohedral LaMnO3Powders.
Symianakis Emmanouil, Malko Daniel, Ahmad Ehsan, Mamede Anne-Sophie, Paul Jean-Francois, Harrison Nicholas, Kucernak Anthony.
The Journal of Physical Chemistry C, vol. 119, pg. 12209-12217 (2015) DOI
- Growth of Ca3Co4O9+δ thin film on sapphire substrate and CGO dense pellet by pulsed laser deposition. Structural, microstructural, surface and electrochemical characterizations.
Chambrier M.H., Huo D., Thoréton V., Rolle A., Mamède A.S., Estradé S., Blach J.F., Pirovano C., Daviero-Minaud S., Roussel P., Peiró F., Vannier R.N.
Solid State Ionics, vol. 273, pg. 13-17 (2015) DOI
- Rational preparation of Ag and Au bimetallic catalysts for the hydrocarbon-SCR of NOx: Sequential deposition vs. coprecipitation method.
More P.M., Nguyen D.L., Dongare M.K., Umbarkar S.B., Nuns N., Girardon J.-S., Dujardin C., Lancelot C., Mamede A.-S., Granger P.
Applied Catalysis B: Environmental, vol. 162, pg. 11-20 (2015) DOI
- Comparative study of aerogels nanostructured catalysts: Ni/ZrO2–SO4 2− and Ni/ZrO2–Al2O3–SO4 2−.
Kamoun N., Younes M. K., Ghorbel A., Mamede A. S., Rives A.
Ionics, vol. 21, pg. 221-229 (2015) DOI
2014- Oxide diffusion in innovative SOFC cathode materials.
Hu Y., Thoréton V., Pirovano C., Capoen E., Bogicevic C., Nuns N., Mamede A.-S., Dezanneau G., Vannier R. N.
Faraday Discuss., vol. 176, pg. 31-47 (2014) DOI
- Highly productive iron molybdate mixed oxides and their relevant catalytic properties for direct synthesis of 1,1-dimethoxymethane from methanol.
Thavornprasert Kaew-arpha, Capron Mickaël, Jalowiecki-Duhamel Louise, Gardoll Olivier, Trentesaux Martine, Mamede Anne-Sophie, Fang Ge, Faye Jérémy, Touati Nadia, Vezin Hervé, Dubois Jean-Luc, Couturier Jean-Luc, Dumeignil Franck.
Applied Catalysis B: Environmental, (2014) DOI
- Glycerol oxidation over gold supported catalysts – “Two faces” of sulphur based anchoring agent.
Skrzyńska Elżbieta, Ftouni Jamal, Mamede Anne-Sophie, Addad Ahmed, Trentesaux Martine, Girardon Jean-Sébastien, Capron Mickaël, Dumeignil Franck.
Journal of Molecular Catalysis A: Chemical, vol. 382, pg. 71-78 (2014) DOI
- TiO2-anatase-supported oxorhenate catalysts prepared by oxidative redispersion of metal Re0 for methanol conversion to methylal: A multi-technique in situ/operando study.
Sécordel Xavier, Tougerti Asma, Cristol Sylvain, Dujardin Christophe, Blanck Dimitri, Morin Jean-Charles, Capron Mickaël, Mamede Anne-Sophie, Paul Jean-François, Languille Marie-Angélique, Brückner Angelika, Berrier Élise.
Comptes Rendus Chimie, vol. 17, pg. 808-817 (2014) DOI
- Structural, textural and acid–base properties of carbonate-containing hydroxyapatites.
Silvester Lishil, Lamonier Jean-François, Vannier Rose-Noëlle, Lamonier Carole, Capron Mickaël, Mamede Anne-Sophie, Pourpoint Frédérique, Gervasini Antonella, Dumeignil Franck.
Journal of Materials Chemistry A, vol. 2, pg. 11073-11090 (2014) DOI
- Oxygen transport kinetics of the misfit layered oxide Ca3Co4O9+d.
Thoréton Vincent, Hu Yang, Pirovano Caroline, Capoen Edouard, Nuns Nicolas, Mamede Anne-Sophie, Dezanneau Guilhem, Yoo Chun-Yul, Bouwmeester Henny J.M., Vannier Rose-Noelle.
J. Mater. Chem. A, vol. 2, pg. 19717-19725 (2014) DOI
- Oxide Ion Transport in Promising Cobaltites for SOC.
Thoréton Vincent, Hu Y., Kehal I., Flandre X., Huo Da, Pirovano C., Rolle A., Capoen E., Nuns N., Mamede A.S., Dezanneau G., Vannier R.N.
Procedia Engineering, vol. 98, pg. 115-120 (2014) DOI
- Novel Synthesis of Gold Nanoparticles Supported on Alkyne-Functionalized Nanosilica.
Fazzini Silvia, Cassani Maria Cristina, Ballarin Barbara, Boanini Elisa, Girardon Jean Sébastien, Mamede Anne-Sophie, Mignani Adriana, Nanni Daniele.
The Journal of Physical Chemistry C, vol. 118, pg. 24538-24547 (2014) DOI
- Effect the solvent evacuation mode on the catalytic properties of nickel-modified sulfated zirconia catalysts: n-hexane isomerization.
Kamoun N., Younes M. K., Ghorbel A., Mamede A. S., Rives A.
Reaction Kinetics, Mechanisms and Catalysis, vol. 111, pg. 199-213 (2014) DOI
- Electron transfers in a TiO2-containing MOR zeolite: synthesis of the nanoassemblies and application using a probe chromophore molecule.
Legrand A., Moissette A., Hureau M., Casale S., Massiani P., Vezin H., Mamede A. S., Batonneau-Gener I.
Physical Chemistry Chemical Physics, vol. 16, pg. 13145 (2014) DOI
2013- Pt Monometallic and Bimetallic Catalysts Prepared by Acid Sol-Gel Method for Liquid Phase Reforming of Bioglycerol.
Doukkali Mohamed El, Iriondo Aitziber, Ibañez José Francisco Cambrá, Jalowiecki-Duhamel Louise, Mamede Anne-Sophie, Dumeignil Franck, Ergueta Pedro Luis Arias.
Journal of Molecular Catalysis A: Chemical, vol. 368-369, pg. 125-136 (2013) DOI
- Synergy between XANES Spectroscopy and DFT to Elucidate the Amorphous Structure of Heterogeneous Catalysts: TiO2-Supported Molybdenum Oxide Catalysts.
Tougerti Asma, Berrier Elise, Mamede Anne-Sophie, La Fontaine Camille, Briois Valérie, Joly Yves, Payen Edmond, Paul Jean-François, Cristol Sylvain.
Angewandte Chemie International Edition, vol. 52, pg. 6440-6444 (2013) DOI
- Composition-Dependent Morphostructural Properties of Ni–Cu Oxide Nanoparticles Confined within the Channels of Ordered Mesoporous SBA-15 Silica.
Ungureanu Adrian, Dragoi Brindusa, Chirieac Alexandru, Ciotonea Carmen, Royer Sébastien, Duprez Daniel, Mamede Anne Sophie, Dumitriu Emil.
ACS Applied Materials < Interfaces, vol. 5, pg. 3010-3025 (2013) DOI
- Nisin adsorption on hydrophilic and hydrophobic surfaces: evidence of its interactions and antibacterial activity.
Karam Layal, Jama Charafeddine, Nuns Nicolas, Mamede Anne-Sophie, Dhulster Pascal, Chihib Nour-Eddine.
Journal of Peptide Science, vol. 19, pg. 377-385 (2013) DOI
- Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile.
Guillon Cyrille, Liebig Carsten, Paul Sebastien, Mamede Anne-Sophie, Holderich Wolfgang F., Dumeignil Franck Yves, Katryniok Benjamin.
Green Chemistry, vol. 15 (11), pg. 3015-3019 (2013) DOI
- Study of nisin adsorption on plasma-treated polymer surfaces for setting up materials with antibacterial properties.
Karam Layal, Jama Charafeddine, Mamede Anne-Sophie, Fahs Ahmad, Louarn Guy, Dhulster Pascal, Chihib Nour-Eddine.
Reactive and Functional Polymers, vol. 73, pg. 1473-1479 (2013) DOI
2012- Comparative study of the texture and structure of aerogel and xerogel sulphated zirconia doped with nickel.
Kamoun N., Younes M. K., Ghorbel A., Mamede A. S., Rives A.
Journal of Porous Materials, vol. 19, pg. 375-381 (2012) DOI
- Sol–gel synthesis combined with solid-solid exchange method, a new alternative process to prepare improved Pd/SiO2-Al2O3 catalysts for methane combustion.
Fessi S., Mamede A.S., Ghorbel A., Rives A.
Catalysis Communications, vol. 27, pg. 109-113 (2012) DOI
- Adsorption of surfactin produced from Bacillus subtilis using nonwoven PET (polyethylene terephthalate) fibrous membranes functionalized with chitosan.
Behary N., Perwuelz A., Campagne C., Lecouturier D., Dhulster P., Mamede A.S.
Colloids and Surfaces B: Biointerfaces, vol. 90, pg. 137-143 (2012) DOI
2011- Novel approach to rhenium oxide catalysts for selective oxidation of methanol to DMM.
Nikonova Olesya A., Capron Mickaël, Fang Ge, Faye Jérémy, Mamede Anne-Sophie, Jalowiecki-Duhamel Louise, Dumeignil Franck, Seisenbaeva Gulaim A.
Journal of Catalysis, vol. 279, pg. 310-318 (2011) DOI
2009- Acetalization of glycerol using mesoporous MoO3/SiO2 solid acid catalyst.
Umbarkar Shubhangi B., Kotbagi Trupti V., Biradar Ankush V., Pasricha Renu, Chanale Jyoti, Dongare Mohan K., Mamede Anne-Sophie, Lancelot Christine, Payen Edmond.
Journal of Molecular Catalysis A: Chemical, vol. 310, pg. 150-158 (2009) DOI
2008- Preparation and characterization of Pd–Co/sulfated zirconia catalysts for no selective reduction by methane.
Rubert Aldo A., Quincoces Claudia E., Mamede Anne-Sophie, Gazzoli Delia, Cabello Carmen, Gloria González M.
Catalysis Communications, vol. 9, pg. 1096-1100 (2008) DOI
- WOx-CeO2 and WOx-Nb2O5 catalysts deactivation during hexane isomerization.
Mamede A.-S., Payen E., Granger P., Florea M., Pârvulescu V. I.
AIChE Journal, vol. 54, pg. 1303-1312 (2008) DOI
- Effect of the nature of the precursor on the morphology of MoO3 thin films spin-coated on Si (100).
Klisinska Anna, Mamede Anne-Sophie, Gaigneaux Eric M.
Thin Solid Films, vol. 516, pg. 2904-2912 (2008) DOI
|
